Quantitative formation and clean metal exchange processes of large void (>5000 Å3) nanobox structures

Michael Schmittel; Horst Ammon; Venkateshwarlu Kalsani; Andreas Wiegrefe; Christoph Michel

doi:10.1039/B207801E

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Quantitative formation and clean metal exchange processes of large void (>5000 Å³) nanobox structures†‡

Michael Schmittel,*^a Horst Ammon,^b Venkateshwarlu Kalsani,^a Andreas Wiegrefe^a and Christoph Michel^a

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* Corresponding authors

^a FB 8 – OC1 Chemie-Biologie, Universität Siegen, Adolf-Reichwein-Str, Siegen, Germany
E-mail: schmittel@chemie.uni-siegen.de
Fax: (+49) 271 740 3270
Tel: (+49) 271 740 4356

^b Institut für Organische Chemie der Universität Würzburg, Am Hubland, Würzburg, Germany

Abstract

The metallosupramolecular assembly of linear and macrocyclic bisphenanthrolines in the presence of Cu⁺ provides nanobox structures with internal volumes of >5000 Å³ when the ligands are designed along the HETPHEN approach.

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Supplementary files

Experimental procedures, ESI-MS spectral data of the prepared complexes, perspective views and dimensions of nanobox 4a, UV-Vis spectra of the nanobox conversion PDF (304K)

Article information

DOI: https://doi.org/10.1039/B207801E
Article type: Communication
Submitted: 09 Aug 2002
Accepted: 20 Sep 2002
First published: 04 Oct 2002

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Chem. Commun., 2002, 2566-2567

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Quantitative formation and clean metal exchange processes of large void (>5000 Å³) nanobox structures

M. Schmittel, H. Ammon, V. Kalsani, A. Wiegrefe and C. Michel, Chem. Commun., 2002, 2566 DOI: 10.1039/B207801E

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