Issue 12, 2002
From the journal:

Chemical Communications

Dehydrodimerization of iodobenzenes to iodinated biaryls

Siegfried R. Waldvogel,*a   Eckhard Aits,a   Christiane Holsta  and  Roland Fröhlicha  

* Corresponding authors

a Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstrasse 40, Münster, Germany
E-mail: waldvog@uni-muenster.de
Fax: 49 251 8339772
Tel: 49 251 8333278

Abstract

The molybdenum pentachloride-mediated oxidative coupling of iodo-substituted electron rich benzenes without the loss of the iodo-substituents is reported. The presented methodology is an environmentally friendly alternative to known thallium(III)- and lead(IV)-reagents. Even 2,2′,6,6′-tetraiodobiphenyl derivatives are easily accessible.

Graphical abstract: Dehydrodimerization of iodobenzenes to iodinated biaryls

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Article information

DOI
https://doi.org/10.1039/B202841G
Article type
Communication
Submitted
21 Mar 2002
Accepted
30 Apr 2002
First published
14 May 2002

Chem. Commun., 2002, 1278-1279

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Dehydrodimerization of iodobenzenes to iodinated biaryls

S. R. Waldvogel, E. Aits, C. Holst and R. Fröhlich, Chem. Commun., 2002, 1278 DOI: 10.1039/B202841G

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