Issue 4, 2002
From the journal:

Chemical Communications

Rhodium-catalysed addition of arylboronic acids to oxabenzonorbornadienes†

Masahiro Murakami*a  and  Hideyuki Igawaa  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Yoshida, Kyoto 606-8501, Japan
E-mail: murakami@sbchem.kyoto-u.ac.jp

Abstract

The facile addition reaction of boronic acids to oxabenzonorbornadienes was achieved using a catalytic amount of a rhodium(I) complex having P(OEt)3 ligands, affording cis-2-aryl-1,2-dihydro-1-naphthol stereoselectively, and in good yield without concomitant deboronation of the boronic acid.

Graphical abstract: Rhodium-catalysed addition of arylboronic acids to oxabenzonorbornadienes

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Article information

DOI
https://doi.org/10.1039/B108808D
Article type
Communication
Submitted
01 Oct 2001
Accepted
11 Dec 2001
First published
30 Jan 2002

Chem. Commun., 2002, 390-391

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Rhodium-catalysed addition of arylboronic acids to oxabenzonorbornadienes

M. Murakami and H. Igawa, Chem. Commun., 2002, 390 DOI: 10.1039/B108808D

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