Issue 18, 2001
From the journal:

Chemical Communications

Palladium–iminophosphine-catalysed carbostannylation of arynes: synthesis of ortho-substituted arylstannanesElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b1/b103745p/

Hiroto Yoshida,‡a   Yuki Honda,a   Eiji Shirakawa*b  and  Tamejiro Hiyama*a  

* Corresponding authors

a Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto, Japan.
E-mail: thiyama@npc05.kuic.kyoto-u.ac.jp

b Graduate School of Materials Science, Japan Advanced Institute of Science and Technology, Asahidai, Tatsunokuchi, Ishikawa, Japan

Abstract

Arynes were found to insert into a carbon–tin bond of alkynyl- and vinylstannanes in the presence of a catalytic amount of a palladium–iminophosphine complex to afford ortho-substituted arylstannanes, which were convertible into a wide variety of 1,2-disubstituted arenes via carbon–carbon bond forming reactions.

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Article information

DOI
https://doi.org/10.1039/B103745P
Article type
Communication
Submitted
25 Apr 2001
Accepted
13 Aug 2001
First published
05 Sep 2001

Chem. Commun., 2001, 1880-1881

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Palladium–iminophosphine-catalysed carbostannylation of arynes: synthesis of ortho-substituted arylstannanes

H. Yoshida, Y. Honda, E. Shirakawa and T. Hiyama, Chem. Commun., 2001, 1880 DOI: 10.1039/B103745P

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