Issue 11, 2000
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Solvent effects on the steric course of the solvolysis of tertiary acyclic derivatives

Paul Müller*a  and  Jean-Claude Rossiera  

* Corresponding authors

a Department of Organic Chemistry, University of Geneva, 30, Quai Ernest Ansermet, Geneva, Switzerland

Abstract

The solvolysis of (R)-3-chloro-3,7-dimethyloctane (2), of the corresponding hydrogen phthalate (S)-4g, and of the p-nitrobenzoate (S )-4h proceeds with up to 87% inversion of configuration in solvents such as methanol or ethanol. The degree of inversion decreases in more dissociating solvents. In 2,2,2-trifluoroethanol (TFE), up to 40% retention of configuration occurs.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B004884O
Article type
Paper
Submitted
19 Jun 2000
Accepted
30 Aug 2000
First published
18 Oct 2000

J. Chem. Soc., Perkin Trans. 2, 2000, 2232-2237

Permissions

Request permissions

Solvent effects on the steric course of the solvolysis of tertiary acyclic derivatives

P. Müller and J. Rossier, J. Chem. Soc., Perkin Trans. 2, 2000, 2232 DOI: 10.1039/B004884O

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements