Issue 7, 2000

Communication of electronic information over nanometer distances with supramolecular transduction. An experimental and density functional investigation

Abstract

We have synthesized a family of conjugated diaminotriazine-functionalized receptors. Variation of distal functionality modulated the affinity of these receptors for flavin, demonstrating efficient electronic communication over a distance of 11 Å. The origin of this communication was explored using DFT methodology. These calculations demonstrate that modulation of recognition in these systems is derived from a complex push–pull type mechanism.

Supplementary files

Article information

Article type
Paper
Submitted
07 Dec 1999
Accepted
13 Apr 2000
First published
01 Jun 2000

J. Chem. Soc., Perkin Trans. 2, 2000, 1309-1313

Communication of electronic information over nanometer distances with supramolecular transduction. An experimental and density functional investigation

R. Deans, A. O. Cuello, T. H. Galow, M. Ober and V. M. Rotello, J. Chem. Soc., Perkin Trans. 2, 2000, 1309 DOI: 10.1039/A909634E

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