Issue 23, 1999
From the journal:

Chemical Communications

Synthesis of an anionic tridentate phosphinoborate and its reaction chemistry with Sn(II)

Alfred A. Barney,   Alan F. Heyduk  and  Daniel G. Nocera  

Abstract

Dichlorophenylborane reacts smoothly with [Li- (tmen)][CH2PPh2] in THF to afford, in good yields, the Li(tmen)+ salt of a novel monoanionic tridentate phosphinoborate, tris(diphenylphosphinomethyl)phenylborate; reaction of the ligand with SnCl2 produces tris(diphenylphosphinomethyl) phenylboratotin(II) chloride, which may be dehalogenated to give the η3 compound, {[PhB- (CH2PPh2)3]Sn}PF6, tris(diphenylphosphinomethyl)- phenylboratotin(II) hexafluorophosphate.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/A906560A
Article type
Paper

Chem. Commun., 1999, 2379-2380

Permissions

Request permissions

Synthesis of an anionic tridentate phosphinoborate and its reaction chemistry with Sn(II)

A. A. Barney, A. F. Heyduk and D. G. Nocera, Chem. Commun., 1999, 2379 DOI: 10.1039/A906560A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements