State of the art ab initio calculations on R(CO)nR (R = H, Me; n = 1–11) indicate that the hypothetical polymer of carbon monoxide, poly-CO, would be energetically less stable than the molecular form only by a few kcal mol–1, making it a plausible stable allotropic form of CO.
G. Frapper, C. Cu, M. Kertesz, J. Halet, J. Saillard, G. Frapper and C. Cu, Chem. Commun., 1997, 2011 DOI: 10.1039/A705721K
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