Abstract
This study describes a novel and convenient way for the preparation of polymer stabilized colloidal silver by an ultra-violet irradiation technique. Methoxypolyethylene glycol (MPEG) generates free radicals in presence of ultra-violet radiation and acts as the reducing agent towards the silver ion. MPEG also serves as a stabilizer of the silver particles formed.
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A. Henglein, J. Phy. Chem. 97 (1993) 5457.
J. Belloni, M. Mostafavi, J. L. Marignier and J. Amblard, J. Imaging Sci. 35 (1991) 68.
M. J. Ware, J. Photogr. Sci. 42 (1994) 153.
G. Schmid, “Clusters and Colloids: From Theory to Application” (VCH, Weinheim, 1994).
J. W. Slot and H. J. Geuze, J. Cell. Biol. 38 (1983) 87.
G. Carotenuto, G. P. Pepe and L. Nicolais, Eur. Phys. J. B 16 (2000) 11.
G. Carotenuto, Appl. Organomet. Chem. 15 (2001) 344.
R. J. Gehr and R. W. Boyd, Chem. Mater. 8 (1996) 1807.
D. Fornasiero and F. Grieser, J. Colloid Interface Sci. 141 (1991) 168.
P. Matejka, B. Vlckova, J. Vohlidal, P. Pancoska and V. Baumrunk, J. Phys. Chem. 96 (1992) 1361.
S. Sanchez-Cortes, J. V. Garcia-Ramos and G. Morcillo, J. Colloid Interface Sci. 167 (1994) 428.
C. H. Monro, W. E. Smith, M. Garner, J. Clarkson and P. C. White, Langmuir 11 (1995) 3712.
U. Nickel, A. Z. Castell, K. Poppl and S. Schneider, ibid. 16 (2000) 9087.
J. P. Abid, A. W. Wark, P. F. Brevet and H. H. Girault, Chem. Commun. 7 (2002) 792.
N. Kometani, H. Doi, K. Asami and Y. Yonezawa, Phys. Chem. Chem. Phys. 4 (2002) 5142.
F. Mafune, J.-Y. Kohno, Y. Takeda, T. Kondow and H. Sawabe, J. Phys. Chem. B 104 (2000) 9111.
J. Zhu, S. Liu, O. Palchik, Y. Koltypin and A. Gedanken, Langmuir 16 (2000) 6396.
Y. Zhou, S. H. Yu, X. P. Cui, C. Y. Wang and Z. Y. Chen, Adv. Mater. 11 (1999) 850.
E. Braun, Y. Eichen, U. Sivan and G. Benyoseph, Nature 391 (1998) 775.
J. Sloan, D. M. Wright, H. G. Woo, S. Bailey, G. Brown, A. P. E. York, K. S. Coleman, J. L. Hutchison and M. L. H. Green, Chem. Commun. (1999) 699.
M. H. Huang, A. Choudrey and P. Yang, ibid. (2000) 1063.
S. Bhattacharyya, S. K. Saha and D. Chakravorty, Appl. Phys. Lett. 76 (2000) 3896.
D. Salz, R. Lamber, M. Wark, A. Baalmann and N. Jaeger, Phys. Chem. Chem. Phys. 1 (1999) 4447.
R. He, X. Qian, J. Yin and Z. Zhu, J. Mater. Chem. 12 (2002) 3783.
V. M. Cepak and C. R. Martin, J. Phys. Chem. B 102 (1998) 9985.
M. Maillard, S. Giorgio and M. P. Pileni, ibid. 107 (2003) 2466.
A. Henglein, Ber. Bunsen-Ges. Phys. Chem. 99 (1995) 903.
M. P. Pileni, New J. Chem. (1998) 693.
S. Link and M. A. El-Sayed, J. Phys. Chem. B 103 (1999) 4212. (b) M. A. EL-SAYED, Acc. Chem. Res. 34 (2001) 257.
S.-H. Kim, G. Medeiros-Rebeiro, D. A. A. Ohlberg, R. S. Williams and J. R. Heath, J. Phys. Chem. B 103 (1999) 10341.
S. Chen, R. S. Ingram, M. J. Hostetler, J. J. Peitron, R. W. Murray, T. G. Schaaff, J. T. Khoury, M. M. Alvarez and R. L. Whetten, Science 280 (1998) 2098.
A. Henglein and D. Meisel, Langmuir 14 (1998) 7392.
P. Mulvaney, in “Semiconductor Nanoclusters-Physical, Chemical and Catalytic Aspects”, edited by P. V. Kamat and D. Meisel (Elsevier Science: Amsterdam, 1997).
U. Kreibig and M. Vollmer, “Optical Properties of Metal Clusters” (Springer, Berlin, 1995).
P. Mulvaney, Langmuir 12 (1996) 788.
M. M. Alvarez, J. T. Khoury, T. G. Schaaff, M. N. Shafigullin, I. Vezmar and R. L. Whetten, J. Phys. Chem. B 101 (1997) 3706.
T. G. Schaaff, M. N. Shafigullin, J. T. Khoury, I. Vezmar, R. L. Whetten, W. G. Cullen, P. N. First, C. Gutierrez-Sing, J. Ascensio and M. J. Jose-Yacaman, ibid. 101 (1997) 7885.
J. R. Heath, C. M. Knobler and D. V. Leff, ibid. 101 (1997) 189.
U. Kreibig, M. Gartz, A. Hilger and H. Hovel, in “Fine Particles Science and Technology,” edited by E. Pelizzatti, (Kluwer Academic Publishers, Boston, 1996).
N. Pradhan, N. R. Jana, K. Mallick and T. Pal, J. Surface Sci. Technol. 16 (2000) 188.
A. Heglein, Ber. Bunsenges. Phys. Chem. 81 (1977) 556.
J. Belloni and M. Mostafavi, in “Metal Clusters in Chemistry,” edited by P. Braunstein, L. A. Oro, and P. R. Raithby (J. Wiley, VCH, III, 1999).
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Mallick, K., Witcomb, M.J. & Scurrell, M.S. Polymer stabilized silver nanoparticles: A photochemical synthesis route. Journal of Materials Science 39, 4459–4463 (2004). https://doi.org/10.1023/B:JMSC.0000034138.80116.50
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DOI: https://doi.org/10.1023/B:JMSC.0000034138.80116.50