Abstract
A method is proposed for calculating the electronegativity of metal atoms in crystalline solids from the thermochemical and structural parameters of inorganic materials. The electronegativities thus calculated are lower than those for metal atoms in a molecular state; the difference decreases as the oxidation state of the metal becomes higher and vanishes for tetravalent metals.
Similar content being viewed by others
REFERENCES
Pauling, L., The Nature of the Chemical Bond: IV. The Energy of Single Bonds and the Relative Electronegativity of Atoms, J. Am. Chem. Soc., 1932, vol. 54, no. 9, pp. 3570–3582.
Gurvich, L.V., Karachevtsev, G.V., Kondrat'ev, V.N., et al., Energii razryva khimicheskikh svyazei. Potentsialy ionizatsii i srodstvo k elektronu (Bond Dissociation Energies, Ionization Potentials, and Electron Affinity), Moscow: Nauka, 1974.
Batsanov, S.S., Eksperimental'nye osnovy strukturnoi khimii (Experimental Basis of Structural Chemistry), Moscow: Standarty, 1986.
Batsanov, S.S., Electronegativity Scale and Effective Atomic Charges in Crystalline Compounds, Zh. Neorg. Khim., 1975, vol. 20, no. 10, pp. 2595–2600.
Batsanov, S.S., Polar Component of the Atomization Energy and Electronegativities of Atoms in Crystals, Izv. Akad. Nauk SSSR, Neorg. Mater., 1990, vol. 26, no. 4, pp. 679–682.
Vieillard, P. and Tardy, Y., A New Scale of Electronegativity of Ions in Oxides and Hydroxides, C. R. Acad. Sci., Ser. II, 1989, vol. 308, no. 17, pp. 1539–1542.
Ionov, S.P. and Sevast'yanov, D.V., Relative Chemical Potential and Structural-Thermochemical Model for Metallic Bonding, Zh. Neorg. Khim., 1994, vol. 39, no. 12, pp. 2061–2067.
Urusov, V.S., Concept of Orbital Electronegativities and Its Place in Energetic Crystal Chemistry, Zh. Strukt. Khim., 1994, vol. 35, no. 1, pp. 111–127.
Villars, P., A Three-Dimensional Structural Stability Diagram for 1011 Binary AB2 Intermetallic Compounds, J. Less-Common Met., 1984, vol. 99, no. 1, pp. 33–43.
Pettifor, D., A Chemical Scale for Crystal-Structure Maps, Solid State Commun., 1984, vol. 51, no. 1, pp. 31–34.
Batsanov, S.S., Thermochemical Electronegativities of Metals, Zh. Fiz. Khim., 2000, vol. 74, no. 2, pp. 331–334.
Narai-Sabo, I., Neorganicheskaya kristallokhimiya (Inorganic Crystal Chemistry), Budapest: Hungarian Acad. Sci., 1969.
Batsanov, S.S., Experimental Determination of the Covalent Radii of Elements, Izv. Akad. Nauk, Ser. Khim., 1995, no. 12, pp. 2349–2354.
CRC Handbook of Chemistry and Physics, Lide, D.R., Ed., Boca Raton: CRC, 1995-1996, 76th ed.
Zemann, J., Madelung Numbers for the Theoretical Structure Type with Mutual Trigonal Prismatic Coordination, Acta Crystallogr., Sect. A: Found. Crystallogr., 1991, vol. 47, no. 6, pp. 851–852.
Templeton, D.H., Madelung Constants and Coordination, J. Chem. Phys., 1953, vol. 21, no. 11, pp. 2097–2098.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Batsanov, S.S. Electronegativities of Metal Atoms in Crystalline Solids. Inorganic Materials 37, 23–30 (2001). https://doi.org/10.1023/A:1026773024407
Issue Date:
DOI: https://doi.org/10.1023/A:1026773024407