Abstract
A new family of rhenium‐based catalysts bearing HZSM‐5 zeolite exhibits remarkable performances for the catalytic dehydrocondensation of methane with CO/CO2 towards ethylene, benzene, and naphthalene in high selectivity of above 90% at 1–3 atm and 973–1023 K. In contrast to Mo/HZSM‐5 catalysts, the EXAFS and TG/DTA/Mass studies reveal that the metallic Re on HZSM‐5 zeolite is a catalytically active and stable phase for the reaction.
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Wang, L., Ohnishi, R. & Ichikawa, M. Novel rhenium‐based catalysts for dehydrocondensation of methane with CO/CO2 towards ethylene and benzene. Catalysis Letters 62, 29–33 (1999). https://doi.org/10.1023/A:1019022316715
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DOI: https://doi.org/10.1023/A:1019022316715