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Crystal and molecular structures of salts of the secondary permethylmetallocenylmethyl cations (C5Me5MC5Me4CHR)+X– (M = Ru, Os; R = Ph, C6F5; X = BF4, PF6)

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Abstract

The structures of tetrafluoroborates of the secondary permethylmetallocenylmethyl cations [Cp*MC5Me4CHR]+ (Cp* = C5Me5; 1b: M = Ru, R = Ph; 1c: M = Os, R = C6F5) were established by X-ray diffraction analysis. The angles of inclination (α) of the C(1)—C(11) bond coordinated to the metal atom with respect to the plane of the C5Me4 ligand are 31.5° and 35.6°, and the M—C(11) distances are 2.506 and 2.401 Å in 1b,c, respectively.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. Z. Kreindlin, K. Yu. Suponitsky, F. M. Dolgushin, Z. A. Starikova & M. I. Rybinskaya

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  1. A. Z. Kreindlin
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  2. K. Yu. Suponitsky
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  3. F. M. Dolgushin
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  4. Z. A. Starikova
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  5. M. I. Rybinskaya
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Kreindlin, A.Z., Suponitsky, K.Y., Dolgushin, F.M. et al. Crystal and molecular structures of salts of the secondary permethylmetallocenylmethyl cations (C5Me5MC5Me4CHR)+X– (M = Ru, Os; R = Ph, C6F5; X = BF4, PF6). Russian Chemical Bulletin 50, 1616–1619 (2001). https://doi.org/10.1023/A:1013038602864

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