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Electrocatalysis of the Oxygen Reaction on Electrodes Prepared Using Disperse Synthetic Diamond Promoted with Cobalt Porphyrin and Its Pyropolymer

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Abstract

The oxygen electroreduction in acid solutions on electrodes of disperse synthetic diamond powder promoted with cobalt tetra(p-methoxyphenyl)porphyrin or its pyrolysis products is studied. A “floating” gas-diffusion electrode and an RDE of isotropic pyrocarbon are used in experiments; in the latter case, the catalyst is immobilized in a Nafion solution. Two types of diamond, with specific area of 5.8 and 170 m2/g, are used. The results are compared with similar data found for promoted acetylene black. A significant effect of the carbon support on electrocatalytical properties of cobalt porphyrin pyrolyzed on it is found.

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Authors and Affiliations

  1. Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117071, Russia

    G. V. Zhutaeva, K. A. Radyushkina & M. R. Tarasevich

  2. Bakul' Institute for Superhard Materials, National Academy of Sciences of Ukraine, Avtozavodskaya ul. 2, Kiev, 254153, Ukraine

    M. A. Marinich & G. P. Bogatyreva

Authors
  1. G. V. Zhutaeva
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  2. K. A. Radyushkina
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  3. M. A. Marinich
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  4. G. P. Bogatyreva
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  5. M. R. Tarasevich
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Zhutaeva, G.V., Radyushkina, K.A., Marinich, M.A. et al. Electrocatalysis of the Oxygen Reaction on Electrodes Prepared Using Disperse Synthetic Diamond Promoted with Cobalt Porphyrin and Its Pyropolymer. Russian Journal of Electrochemistry 37, 1059–1064 (2001). https://doi.org/10.1023/A:1012371030158

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  • DOI: https://doi.org/10.1023/A:1012371030158

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