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Guanidine in the synthesis of perfluoroalkylpyrimidines and perfluoroalkyl-s-triazines

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Russian Chemical Bulletin Aims and scope

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Abstract

Perfluoro-2-methylpent-2-ene and perfluoro-5-azanon-4-ene react with guanidine hydrochloride in the presence of triethylamine to give 2-amino-6-fluoro-4-pentafluoroethyl-5-trifluoromethylpyrimidine and 2-amino-4,6-bis(heptafluoropropyl)-1,3,5-triazine, respectively. The structure of the former product was confirmed by X-ray diffraction analysis.

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Authors and Affiliations

  1. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent"eva, 630090, Novosibirsk, Russian Federation

    G. G. Furin, Yu. V. Gatilov & I. Yu. Bagryanskaya

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    E. L. Zhuzhgov

Authors
  1. G. G. Furin
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  2. Yu. V. Gatilov
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  3. I. Yu. Bagryanskaya
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  4. E. L. Zhuzhgov
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Furin, G.G., Gatilov, Y.V., Bagryanskaya, I.Y. et al. Guanidine in the synthesis of perfluoroalkylpyrimidines and perfluoroalkyl-s-triazines. Russian Chemical Bulletin 50, 476–479 (2001). https://doi.org/10.1023/A:1011317425405

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  • DOI: https://doi.org/10.1023/A:1011317425405

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