Abstract
Surface oxidation of ultra-high molecular weight polyethylene (UHMWPE) powder has an influence on the mixing procedure of chopped fibres and UHMWPE powder. Due to this oxidation hydrogen bonds can be formed between the fibres and powder particles, leading to a more homogeneous fibre–powder mixture. This treatment improves the fibre–matrix interface and thus the physical properties of the composite. Chromic acid treatment also has an influence on the mechanical and tribological properties of the aramid–UHMWPE composite. Although only a relatively small improvement is observed in the modulus, yield stress and stress at break, of 33, 17 and 9%, respectively, a substantial enhancement in wear resistance of 117% is observed.
Similar content being viewed by others
References
J. de Boer, PhD thesis, University of Groningen, The Netherlands (1984).
J. H. Dumbleton, “Tribology of natural and artificial joints” (Elsevier Amsterdam, 1981).
J. R. Cooper, D. Dowson and J. Fisher, Wear 162-4 (1993) 378.
J. S. B. Gunther and R. M. Rose, J. Long-term Eff. Medical Impl. 4 (1994) 157.
A. Wang, D. C. Sun, C. Stark and J. H. Dumbleton, Wear, 181-3 (1995) 241.
A. Wang, A. Essner, C. Stark and J. H. Dumbleton, Biomaterials 17 (1996) 865.
N. Al Saffar, P. A. Revell, H. A. Khwaja and W. Bonfield, J. Mater. Sci. Mater. Med. 6 (1995) 762.
K. J. Mergevicius, T. W. Bauer, J. T. Mcmahon, S. A. Brown and K. Merritt, J. Bone Joint Surg. 76a (1994) 1664.
J. M. HofstÉ, H. H. G. Smit and A. J. Pennings, Polym. Bull. 37 (1996) 385.
A. A. Berlin, in “Principles of polymer composites”, edited by G. Henrici-Olive and S. Olive (Springer-Verlag, 1986).
D. M. Bigg, Polym. Comp. 8 (1987) 115.
D. B. Eagles, B. F. Blumentritt and S. L. Cooper, J. Appl. Polym. Sci. 20 (1976) 435.
H. H. Yang, in “Kevlar aramid fiber” (J Wiley, New York, 1992) p. 70.
J. Kalantar and L. T. Drzal, J. Mater. Sci. 25 (1990) 4186.
L. C. Sawyer and M. Jaffe, ibid. 21 (1986) 1897.
R. J. Morgan, C. O. Pruneda and W. J. Steele, J. Polym. Sci. Polym. Phys. 21 (1983) 1757.
M. G. Dobb, D. J. Johnson and B. P. Saville, ibid. 15 (1977) 2201.
U. Plawsky, M. Londschien and W. Michaeli, J. Mater. Sci. 31 (1996) 6043.
G. S. Sheu and S. S. Shyu, Comp. Sci. Technol. 52 (1994) 489.
F. Poncin-Epaillard, B. Chevet and J. C. Brosse, J. Appl. Polym. Sci. 52 (1994) 1047.
G. S. Sheu and S. S. Shyu, J. Adhes Sci. Technol. 8 (1994) 1027.
K. KÜpper and P. Schwartz, ibid. 5 (1991) 165.
H. Salehi-Mobarakey, A. Ait-kadi and J. Brisson, Polym. Eng. Sci. 36 (1996) 779.
N. Tsubokawa and T. Oyanagi, React. Polym. 22 (1994) 47.
P. Lee-Sullivan, K. S. Chian, C. Y. Yue and H. C. Looi, J. Mater. Sci. Lett. 13 (1994) 305.
C. T. Chou and L. S. Penn, J. Adhes. 36 (1991) 125.
F. P. M. Mercx and P. J. Lemstra, Polym. Comm. 31 (1990) 252.
L. S. Penn and B. Jutis, J. Adhes. 30 (1989) 67.
S. L. Tidrick and J. L. Koenig, ibid. 29 (1989) 43.
M. Takayanagi, S. Ueta, W. Y. Lei and K. Koga, Polym. J. 19 (1987) 467.
M. Takayanagi, T. Kajiyama and T. Katayose, J. Appl. Polym. Sci. 27 (1982) 3903.
F. P. M. Mercx PhD thesis, University of Eindhoven, The Netherlands (1996).
B. Takens, PhD thesis, University of Twente, The Netherlands (1997).
R. K. Wells, J. P. S. Badyal, I. W. Drummond, K. S. Robinson and F. J. Street, J. Adhes. Sci. Technol. 7 (1993) 1129.
J. F. Carley and P. T. Kitze, Polym. Eng. Sci. 20 (1980) 330.
H. Steinhauser and G. Ellinghorst, Angew. Makromol. Chem. 120 (1984) 177.
F. Garbassi, E. Occhiello and F. Polato, J. Mater. Sci. 22 (1987) 207.
M. S. Silverstein, O. Breuer and H. Dodiuk, J. Appl. Polym. Sci. 52 (1994) 1785.
M. S. Silverstein and O. Breuer Polymer 34 (1993) 3421.
F. P. M. Mercx, A. Bezina, A. D. Langeveld and P. J. Lemstra, J. Mater. Sci. 28 (1993) 753.
M. S. Silverstein and O. Breuer, ibid. 28 (1993) 4718.
S. B. Bentjen, D. A. Nelson, B. J. Tarasevich and P. C. Rieke, J. Appl. Polym. Sci. 44 (1992) 965.
D. Briggs, D. M. Brewis and M. B. Konieczo, J. Mater. Sci. 11 (1976) 1270.
K. Friedrich, “Friction and wear of polymer composites” (Elsevier, Amsterdam, 1986) p. 240.
Y. Termonia, J. Mater. Sci. Lett. 12 (1993) 732.
Idem, J. Mater. Sci. 25 (1990) 4644.
Idem, ibid., 22 (1987) 504.
D. Hull, in “An introduction to composite materials” (Cambridge University Press, 1981) p. 36.
J. M. HofstÉ, M. J. E. Kersten, J. Van Turnhout and A. J. Pennings, in press.
J. K. Lancaster, J. Appl. Phys. J. Phys. D 1 (1968) 549.
K. Tanaka and S. Kawakami, Wear 79 (1982) 221.
T. A. Blanchet, Tribol. Transact. 38 (1995) 821.
A. Wang, D. C. Sun, C. Stark and J. H. Dumbleton, Wear 181-3 (1995) 241.
J. K. Lancaster, Plast. Polym. 21 (1973) 297.
B. Briscoe, Tribol. Int. 14 (1981) 231.
I. M. Hutchings, “Tribology: friction and wear of engineering materials” (Arnold, Cambridge, 1992) p. 125.
S. R. Holmes-Farley, R. H. Reamey, R. Nuzzo, T. J. Mccarthy and G. M. Whitesides, Langmuir 3 (1987) 799.
S. R. Holmes-Farley and G. M. Whitesides, ACS. Polym. Mater. Sci. Eng. Prepr. 53 (1985) 127.
J. R. Rasmussen, D. E. Bergbreiter and G. M. Whitesides, J. Amer. Chem. Soc. 99 (1977) 4746.
J. Wang, D. Feng, H. Wang, M. Rembold and F. Thommen, J. Appl. Polym. Sci. 50 (1993) 585.
T. Yasuda, M. Miyama and H. Yasuda, Langmuir 8 (1992) 1425.
T. Yasuda, T. Okuno, K. Yoshida and H. Yasuda, J. Polym. Sci. Polym. Phys. 26 (1988) 1781.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Hofste, J., Schut, J. & Pennings, A. The effect of chromic acid treatment on the mechanical and tribological properties of aramid fibre reinforced ultra-high molecular weight polyethylene composite. Journal of Materials Science: Materials in Medicine 9, 561–566 (1998). https://doi.org/10.1023/A:1008957324878
Issue Date:
DOI: https://doi.org/10.1023/A:1008957324878