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Vapor–Liquid Equilibria of CFC Alternative Refrigerant Mixtures: Trifluoromethane (HFC-23)+Difluoromethane (HFC-32), Trifluoromethane (HFC-23)+Pentafluoroethane (HFC-125), and Pentafluoroethane (HFC-125)+1,1-Difluoroethane (HFC-152a)

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Abstract

Isothermal vapor–liquid equilibria for three binary mixtures of CFC alternative refrigerants were determined in an equilibrium apparatus in which both phases were continuously recirculated. The pressures and vapor and liquid compositions were measured for the binary systems trifluoromethane (HFC-23)+difluoromethane (HFC-32) and trifluoromethane (HFC-23)+pentafluoroethane (HFC-125) at 283.15 and 293.15 K and pentafluoroethane (HFC-125)+1,1-difluoroethane (HFC-152a) at 293.15 K. The experimental data were correlated with the Peng–Robinson–Stryjek–Vera equation of state using the Huron–Vidal original mixing rule. Calculated results with this equation showed good agreement with the experimental data.

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REFERENCES

  1. H. Orbey and S. I. Sandler, Modeling Vapor-Liquid Equilibria-Cubic Equation of State and Their Mixing Rules (Cambridge University Press, Cambridge, 1998), pp. 19-74.

    Google Scholar 

  2. B.-G. Lee, J.-Y. Park, J. S. Lim, S. Y. Cho, and K. Y. Park, J. Chem. Eng. Data 44:190 (1999).

    Google Scholar 

  3. J. S. Lim, J.-Y. Park, B.-G. Lee, and J.-D. Kim, J. Chem. Eng. Data (in press).

  4. E. Y. Chung and M. S. Kim, J. Chem. Eng. Data 42:1126 (1996).

    Google Scholar 

  5. Y. Higashi, Int. J. Thermophys. 16:1175 (1995).

    Google Scholar 

  6. M. Nagel and K. Bier, Int. J. Refrig. 18:534 (1995).

    Google Scholar 

  7. H. Nishiumi, A. Hidetaka, and A. Sadanobu, Korea J. Chem. Eng. 14:359 (1997).

    Google Scholar 

  8. R. Stryjek and J. H. Vera, Can. J. Chem. Eng. 64:323 (1986).

    Google Scholar 

  9. M. Huron and J. Vidal, Fluid Phase Equil. 3:255 (1979).

    Google Scholar 

  10. M. Huber, J. Gallagher, M. O. McLinden, and G. Morrison, Thermodynamic Properties of Refrigerants and Refrigerant Mixtures Database, REFPROP V.6.01 (NIST, Boulder, CO, 1996).

    Google Scholar 

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Authors and Affiliations

  1. Division of Environment and Process Technology, Korea Institute of Science and Technology (KIST), P.O. Box 131, Cheongryang, Seoul, 130-650, Korea

    J. S. Lim, J.-Y. Park & B.-G. Lee

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  1. J. S. Lim
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  2. J.-Y. Park
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  3. B.-G. Lee
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Lim, J.S., Park, JY. & Lee, BG. Vapor–Liquid Equilibria of CFC Alternative Refrigerant Mixtures: Trifluoromethane (HFC-23)+Difluoromethane (HFC-32), Trifluoromethane (HFC-23)+Pentafluoroethane (HFC-125), and Pentafluoroethane (HFC-125)+1,1-Difluoroethane (HFC-152a). International Journal of Thermophysics 21, 1339–1349 (2000). https://doi.org/10.1023/A:1006653309953

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  • DOI: https://doi.org/10.1023/A:1006653309953

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