Rapid and Efficient Redox Processes within 2D Covalent Organic Framework Thin Films

DeBlase, Catherine R.; Hernández-Burgos, Kenneth; Silberstein, Katharine E.; Rodríguez-Calero, Gabriel G.; Bisbey, Ryan P.; Abruña, Héctor D.; Dichtel, William R.

doi:10.1021/acsnano.5b00184

Title: Rapid and Efficient Redox Processes within 2D Covalent Organic Framework Thin Films

Journal Article · Wed Feb 11 00:00:00 EST 2015 · ACS Nano

DOI:https://doi.org/10.1021/acsnano.5b00184· OSTI ID:1370446

DeBlase, Catherine R. ^[1]; Hernández-Burgos, Kenneth ^[1]; Silberstein, Katharine E. ^[1]; Rodríguez-Calero, Gabriel G. ^[1]; Bisbey, Ryan P. ^[1]; Abruña, Héctor D. ^[1]; Dichtel, William R. ^[1]

Cornell Univ., Ithaca, NY (United States). Baker Lab.

Two-dimensional covalent organic frameworks (2D COFs) are ideally suited for organizing redox-active subunits into periodic, permanently porous polymer networks of interest for pseudocapacitive energy storage. Currently, we describe a method for synthesizing crystalline, oriented thin films of a redox-active 2D COF on Au working electrodes. The thickness of the COF film was controlled by varying the initial monomer concentration. A large percentage (80–99%) of the anthraquinone groups are electrochemically accessible in films thinner than 200 nm, an order of magnitude improvement over the same COF prepared as a randomly oriented microcrystalline powder. As a result, electrodes functionalized with oriented COF films exhibit a 400% increase in capacitance scaled to electrode area as compared to those functionalized with the randomly oriented COF powder. These findings demonstrate the promise of redox-active COFs for electrical energy storage and highlight the importance of controlling morphology for optimal performance.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Energy Materials Center at Cornell (EMC2)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: SC0001086; FG02-87ER45298; PHY-936384; DMR-1332208

OSTI ID:: 1370446

Journal Information:: ACS Nano, Vol. 9, Issue 3; Related Information: Emc2 partners with Cornell University (lead); Lawrence Berkeley National Laboratory; ISSN 1936-0851

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 279 works

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Title: Rapid and Efficient Redox Processes within 2D Covalent Organic Framework Thin Films

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