Atomically Precise Strategy to a PtZn Alloy Nanocluster Catalyst for the Deep Dehydrogenation of n-Butane to 1,3-Butadiene

Camacho-Bunquin, Jeffrey; Ferrandon, Magali S.; Sohn, Hyuntae; Kropf, A. Jeremy; Yang, Ce; Wen, Jianguo; Hackler, Ryan A.; Liu, Cong; Celik, Gokhan; Marshall, Christopher L.; Stair, Peter C.; Delferro, Massimiliano

doi:10.1021/acscatal.8b02794

Title: Atomically Precise Strategy to a PtZn Alloy Nanocluster Catalyst for the Deep Dehydrogenation of n-Butane to 1,3-Butadiene

Journal Article · Thu Sep 27 00:00:00 EDT 2018 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.8b02794· OSTI ID:1483666

^[1]; Ferrandon, Magali S. ^[1]; Sohn, Hyuntae ^[1]; Kropf, A. Jeremy ^[1]; Yang, Ce ^[1]; Wen, Jianguo ^[1];

^[2];

^[1]; Celik, Gokhan ^[1];

^[1]; Stair, Peter C. ^[3];

^[1]

Argonne National Lab. (ANL), Lemont, IL (United States)
Northwestern Univ., Evanston, IL (United States)
Argonne National Lab. (ANL), Lemont, IL (United States); Northwestern Univ., Evanston, IL (United States)

Here, the development of on-purpose 1,3-butadiene (BDE) technologies remains an active area in catalysis research, because of the importance of BDE in industrial polymer production. Here, we report on a nonoxidative dehydrogenation catalyst for the production of BDE prepared by atomically precise installation of platinum sites on a Zn-modified SiO₂ support via atomic layer deposition (ALD). In situ reduction X-ray absorption spectroscopy (XAS), X-ray photoelectron spectroscopy (XPS), CO chemisorption, and high-angle annular dark-field (HAADF) scanning transmission electron microscopy (STEM) imaging of activated PtZn/SiO₂, revealed the formation of a uniform, well-distributed subnanometer- to nanometer-sized PtZn (1.2 ± 0.3 nm) alloy as the active catalytic species.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1483666

Journal Information:: ACS Catalysis, Vol. 8, Issue 11; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 51 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
1
3-butadiene
alloy
atomic layer deposition
nanoparticles
non-oxidative dehydrogenation

Title: Atomically Precise Strategy to a PtZn Alloy Nanocluster Catalyst for the Deep Dehydrogenation of n-Butane to 1,3-Butadiene

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