Elsevier

Synthetic Metals

Volume 93, Issue 2, 15 March 1998, Pages 89-96
Synthetic Metals

Multiple internal reflection FT-IR spectroscopy (MIRFTIRS) study of the electrochemical synthesis and redox process of poly (1,5-diaminonaphthalene)

https://doi.org/10.1016/S0379-6779(97)03946-5Get rights and content

Abstract

The electrooxidation of 1,5-diaminonaphthalene (1,5-DAN) in acidic acqueous, methanol and organic media leads to polymer film on glassy carbon and Pt electrodes. The in situ infrared study during film growth and X-ray photoelectron spectroscopy (XPS) analysis indicate that the polymer structure consists of amine (-NH-C) and imine (-N=C) units, bearing free -NH2 groups in the chain. The polymer structure was confirmed by a multiple internal reflection FT-IR spectroscopy (MIRFTIRS) study of the film redox process and by the ability of poly(1,5-DAN) film to chelate copper ions.

References (19)

  • M.C. Pham et al.

    Synth. Met.

    (1994)
  • M.C. Pham et al.

    Synth. Met.

    (1994)
  • M.A. Azzem et al.

    Synth. Met.

    (1994)
  • C.S. Jin et al.

    Synth. Met.

    (1995)
  • K. Jackowska et al.

    J. Electroanal. Chem.

    (1995)
  • A.G. Moritz

    Spectrochim. Acta

    (1960)
  • Zhao Ping et al.

    Electrochim. Acta

    (1996)
  • M. Mostefai
  • N. Oyama et al.

    Synth. Met.

    (1989)
There are more references available in the full text version of this article.

Cited by (0)

View full text
Copyright © 1998 Published by Elsevier B.V.