Crystallographic study of interaction between adspecies on metal surfaces
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Adsorption and valence electronic states of nitric oxide on metal surfaces
2021, Surface Science ReportsCitation Excerpt :In the surface science community, the adsorption and reaction of nitric oxide on metal surfaces has been studied intensively under well-defined conditions, aiming at the atomic-scale understanding of the catalytic processes [7–15]. In comparison with comprehensive experimental and theoretical studies concerning CO adsorbed on metal surfaces [7,8,16–21], the chemical and physical properties of NO on surfaces are rather poorly understood [10]. The difficulty in understanding of NO–metal interactions can be attributed to high chemical reactivity of NO due to its unpaired electron.
Carbon-monoxide adsorption and dissociation on Nb(1 1 0) surface
2015, Applied Surface ScienceCombined experiment and theory approach in surface chemistry: Stairway to heaven?
2015, Surface ScienceCitation Excerpt :Clearly, the strong interaction of the AM additives with coadsorbed reactants, whose electronic, structural, vibrational and energetic properties are greatly modified, is at the heart of the promoter action of the AMs. A prototypical system, which has been widely investigated in this context, is the coadsorption of AM with CO on transition metal surfaces [38–40]. The strong interaction between these species is manifested by their mutual thermal stabilization [41] in combination with a profound lowering of the CO stretching frequency, which is explained with a weakening of the internal CO bonding and therefore a modification of the chemical activity of CO [38,42].
In situ study of catalytic CO oxidation on ultrathin MgO film supported Pd nanoparticles by sum frequency generation: size and site effects
2023, Physical Chemistry Chemical PhysicsSurfaces and interfaces
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