Electrochemical synthesis of tertiary phosphine from organic halides and chlorophosphines

doi:10.1016/S0040-4039(00)96000-3

Tetrahedron Letters

Volume 28, Issue 17, 1987, Pages 1885-1886

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Abstract

The electrochemical synthesis of a wide range of tertiary mono- and diphosphines has been achieved in very simple and mild conditions, in an undivided electrolytic cell with a sacrificial anode of magnesium.

The electroreduction of Ph₂PCl or PhPCl₂ in presence of alkyl halides in a one-compartment cell with a sacrificial Mg anode affords the corresponding mono- or dialkylated tertiary phosphines in good yields.

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Electrochemical synthesis of tertiary phosphine from organic halides and chlorophosphines

Abstract

Tetrahedron Lett.

Tetrahedron Lett.

Tetrahedron Lett.