Novel hexa- and pentacoordinate sulfur compounds: Dichlorodiazapersulfurane and its persulfonium salt from 1,11-(methanoaminomethano)-5H,7H-dibenzo[b,g] [1,5]thiazocine

doi:10.1016/S0040-4039(00)94419-8

Tetrahedron Letters

Volume 31, Issue 7, 1990, Pages 1019-1022

https://doi.org/10.1016/S0040-4039(00)94419-8 Get rights and content

Abstract

A new sulfur-bridged diaza[3.3]metacyclophane, 1,11-(methanoaminomethano)−5H,7Hdibenzo[b,g][1,5]thiazocine (4) has been synthesized. The reaction of 4 with t-BuOCl or N-chlorobenzotriazole gave a novel hypervalent sulfur compound, dichlorodiazapersulfurane which was easily converted to the corresponding persulfonium ion.

The reaction of 1,11-(methanoaminomethano)-5H,7H-dibenzo-[b,g][1,5]thiazocine with t-BuOCl or N-chlorobenzotriazole gave a novel hypervalent sulfur compound, dichlorodiazapersulfurane 1 which was easily converted to the corresponding persulfonium ion 2.

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Novel hexa- and pentacoordinate sulfur compounds: Dichlorodiazapersulfurane and its persulfonium salt from 1,11-(methanoaminomethano)-5H,7H-dibenzo[b,g] [1,5]thiazocine

Abstract

Sulfurane Chemistry

J. Am. Chem. Soc.

J. Am. Chem. Soc.

J. Am. Chem. Soc.

Angew. Chem. Int. Ed. Engl.