Rhodium catalysed [2+2+2] cycloadditions of acetylenes

https://doi.org/10.1016/S0040-4039(00)87433-XGet rights and content

Abstract

Wilkinson's catalyst RhCl(PPh3)3 is an effective catalyst (0.5 – 2 mole %) for the rapid intermolecular trimerisation of 1,6-heptadiynes with monoacetylenes under mild conditions.

References (6)

  • L.S. Meriwether et al.

    J. Org. Chem.

    (1961)
    V.O. Reikhsfel'd et al.

    Russ. Chem. Revs.

    (1966)
  • Y. Wakatsuki et al.

    Synthesis

    (1976)
    Y. Wakatsuki et al.

    J. Chem. Soc.

    (1978)
    H. Bonnemann

    Angew. Chem. Int. Ed. Engl.

    (1978)
  • K.P.C. Vollhardt

    Accts. Chem. Res.

    (1977)
    E.R.F. Gesing et al.

    J. Organomet. Chem.

    (1981)
    G. Ville et al.

    J. Am. Chem. Soc.

    (1981)
    T.R. Gadek et al.
There are more references available in the full text version of this article.

Cited by (119)

  • Recent advances in stereoselective [2+2+2] cycloadditions

    2015, European Journal of Organic Chemistry
  • Transition Metal Promoted Synthesis of Isoindoline Derivatives

    2022, More Synthetic Approaches to Nonaromatic Nitrogen Heterocycles, Volume 2
View all citing articles on Scopus
View full text