Synthesis of a new family of protected 1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid derivatives with thioctic acid pending arms

doi:10.1016/j.tetlet.2012.08.150

Tetrahedron Letters

Volume 53, Issue 45, 7 November 2012, Pages 6115-6118

https://doi.org/10.1016/j.tetlet.2012.08.150 Get rights and content

Abstract

The synthesis and characterization of a new family of ester protected N-substituted [1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid (H3DO3A) derivatives containing a pendant thioctic acid (α lipoic acid, LA) are reported. These compounds (DO3A^tBu-NLA, DO3A^tBu-NMeNLA, and DO3A^tBu-NEtNLA) are suitable for the functionalization of gold surfaces with rare-earth complexes.

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Acknowledgment

The authors are grateful to ‘École Normale Supérieure de Lyon’ for the thesis Grant allocation to AdlR.

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Synthesis of a new family of protected 1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid derivatives with thioctic acid pending arms

Abstract

Graphical abstract

Section snippets

Acknowledgment

Coord. Chem. Rev.

J. Am. Chem. Soc.

J. Biol. Inorg. Chem.

Acc. Chem. Res.

Coord. Chem. Rev.

Chem. Rev.

Langmuir

Chem. Eur. J.

J. Biol. Inorg. Chem.

Eur. J. Inorg. Chem.

Tetrahedron Lett.

J. Am. Chem. Soc.

J. Biol. Inorg. Chem.

J. Am. Chem. Soc.

Chem. Rev.

Coord. Chem. Rev.

Chem. Rev.

Coord. Chem. Rev.

J. Biol. Inorg. Chem.

Chem. Rev.

Chem. Commun.

Chem. Soc. Rev.

Chem. Rev.

Chem. Rev.

Acc. Chem. Res.

Chem. Commun.

Dalton Trans.

Chem. Commun.

Chem. Commun.

New J. Chem.