Characterization of Fe2O3 doping on structure, optical and luminescence properties of magnesium aluminosilicate-based glasses
Introduction
In recent years, with the continuous integration of optics, electronic information science, and new material science, optical glass acting as the basic material of optoelectronics has a wide range of applications in military and civilian fields. Especially, the optical glass materials can be applied in tunable solid-state lasers and luminescence materials for its high permeability in the visible region [1], [2], [3], [4]. In generally, the optical glass with excellent performance can be obtained by adding some modifiers such as alkali metals, alkaline earth metals, rare earth, and transition metal oxides [5, 6]. Due to the unique electronic layer structure, transition metal oxides are widely used in various glasses to improve their structure and properties, especially the optical and fluorescent properties of glass. For instance, Mohamed et al. [7] reported the effects of transition metal oxides (such as NiO, CuO, CoO, Bi2O3) on the optical and electrical properties of 60PbO-20Bi2O3–20MxOy mol% (MxOy = B2O3 or SiO2 or P2O5) glasses. They found that the introduction of the transition metal oxide reduced the width of the bandgap in the energy band structure, making the glass transition from an insulator to a semiconductor. Also, Bates used the coordination field theory for the first time to systematically study the absorption spectra of transition metal ions-doped silicate glasses [8]. The results showed that the coordination field can be changed by adjusting the glass matrix, thereby reducing the polarization effect of oxygen ion groups on the transition metal ions in the glass, which led to the variation of glass luminous properties. Hongli Wen et al. [9] prepared P2O5-Al2O3-SiO2-GeO2-Li2O glasses doped with 3d-transition metal ions and investigated their optical properties. Félix-Quintero et al. [10] reported the photoluminescence of Mn2+ doped zinc phosphate glasses. They all found that the change of transition metal ions coordination caused the variation in the optical and luminescence properties of glass.
As a kind of transition metal oxide, Fe2O3 has been usually added into kinds of glasses to reduce the melting temperature or used as a nucleating agent to induce nucleation and crystallization in glass-ceramics [11], [12], [13]. In the glass, iron is usually present in two valence states, i.e., Fe2+ and Fe3+. Ferrous ion (Fe2+) can be used as a network modifier to destroy the network structure of glass, while ferric ion (Fe3+) can form nets and enhance the glass networks [14, 15]. Besides, a large number of studies have also shown that Fe2O3 can significantly reduce the optical band gap of glass and promote the transition of glass from insulator to semiconductor [16], [17], [18], [19], [20]. However, we find that only a small amount of work has focused on the research of luminescence properties for Fe2O3-doped glass [21, 22]. In our previous works [23], we found that Fe2O3 can promote the formation of a single cordierite phase from the magnesium aluminosilicate-based glasses. Although the prepared glass-ceramic has a lower fluorescence lifetime, it can be used as a potential substitute material for fluorescent materials in white light-emitting diode device. Therefore, the present investigation is taken up to prepare, characterize, and study the impact of Fe2O3 content on structural and properties in MgO-Al2O3-SiO2-B2O3 (MASB) glasses, especially for the optical and fluorescence performance. We replaced Al2O3 with a small amount of Fe2O3 to prepare Fe2O3-doped MASB glasses. The glass structure, physical-chemical, optical, and luminescent properties of Fe2O3-doped MASB glasses were analyzed, and we hope that the obtained results can provide some useful guidance for the development of fluorescent materials.
Section snippets
Glass preparation
Powders of analytical reagent grade (Guo-Yao Co. Ltd., Shanghai, China), comprising magnesium oxide (MgO), aluminum oxide (Al2O3), silicon dioxide (SiO2), boric acid (H3BO3), and ferric oxide (Fe2O3), were used as the starting materials. The nominal composition of 20MgO-(20-x)Al2O3–57SiO2–3B2O3-xFe2O3 (x = 0, 0.1, 0.25, 0.5, and 1.0 mol%) were prepared by the conventional melt quenching technique, and the corresponding glass composition was named after MASB-F0, MASB-F1, MASB-F2, MASB-F3,
Analysis of XRD and DSC
Fig. 1(a) shows the prepared glasses with different Fe2O3 contents. As the Fe2O3 content increases, the color of glasses deepens gradually, i.e., from white to light yellow, yellow, and tends to tawny at last. This phenomenon is mainly caused by the colorization effect of Fe3+. Meanwhile, the transparency of the prepared glasses also decreases. Additionally, the XRD scattering spectrum of MASB glasses doped with different Fe2O3 content is also shown in Fig. 1(a). It is found that all samples
Conclusions
In the present study, a Fe2O3-doped aluminosilicate-based glass system was prepared by the traditional high-temperature melting method. The prepared glass samples are characterized by structural (DTA, XRD, FTIR), physical-chemical (density, refractive index, Vickers hardness, and acid resistance), and spectroscopic (optical absorption and photoluminescence) studies. Based on the analysis of all the studies for these glass materials, the conclusions have drawn as follows:
1) With the addition of
Data availability
The raw/processed data required to reproduce these findings cannot be shared at this time as the data also forms part of an ongoing study.
Credit author statement
Qianxing Huang: Conceptualization, Methodology, Writing-Original draft preparation.
Taoyong Liu: Investigation, Conceptualization, Resources, Data curation.
Xuefeng Shen: Software, Validation.
Xiuying Li: Investigation, Resources.
Anxian Lu: Writing-Review & Editing, Project administration, Supervision.
Yi Gu: Project administration, Supervision.
Declaration of Competing Interest
The authors declared no interest conflicts.
Acknowledgments
This work has been supported by the National Natural Science Foundation of China (no. 51672310), the Fundamental Research Funds for the Central Universities of Central South University (2019zzts934), the Natural Science Foundation of Jiangxi Province (20202BABL204020); Scientific and technological project of Jingdezhen (20192GYZD008-34).
References (64)
- et al.
Nd3+ doped magnesium zinc sulfophosphate glass: new candidate for up-conversion solid state laser host
Opt. Mater.
(2020) - et al.
Enhanced red luminescent PBTNAEu glasses for solid state lasers
J. Lumin.
(2020) - et al.
Laser-assisted embedding of all-glass optical fiber sensors into bulk ceramics for high-temperature applications
Opt. Laser Technol.
(2020) - et al.
Non-alkali glass substrate with improved mechanical properties for display devices
J. Non-Cryst. Solid.
(2019) - et al.
Luminescence and scintillation properties of CuO-doped SiO2-B2O3-La2O3 glass
Opt. Mater.
(2019) - et al.
Photoluminescence and semiconducting behavior of Fe, Co, Ni and Cu implanted in heavy metal oxide glasses
J. Mater. Res. Technol.
(2016) - et al.
Optical properties of 3d transition metal ion-doped aluminophosphate glasses
J. Lumin.
(2019) - et al.
RGB emission of Mn2+ doped zinc phosphate glass
J. Non-Cryst. Solid.
(2017) - et al.
Crystallization behavior of glass ceramics prepared from the mixture of nickel slag, blast furnace slag and quartz sand
J. Non-Cryst. Solid.
(2010) - et al.
Effects of Fe2O3 content on microstructure and mechanical properties of CaO-Al2O3-SiO2 system
Trans. Nonferrous Met. Soc. China
(2015)
Redox equilibria and coordination of Fe2+ and Fe3+ in silicate glasses from 57Fe mossbauer spectroscopy
J. Non-Cryst. Solid.
Effect of Fe2O3 on non-isothermal crystallization of CaO-MgO-Al2O3-SiO2 glass
Trans. Nonferrous Met. Soc. China
Structural changes in the ZnF2-Bi2O3-GeO2 glass system doped with Fe2O3 by spectroscopic and dielectric investigations
J. Phys. Chem. Solid.
Magnetic and spectroscopic studies of an iron lithium calcium silicate glass and ceramic
J. Non-Cryst. Solid.
Glass forming ability, structure and properties of Cr2O3-Fe2O3 co-doped MgO-Al2O3-SiO2-B2O3 glasses and glass-ceramics
J. Non-Cryst. Solid.
EPR, FTIR, optical absorption and photoluminescence studies of Fe2O3 and CeO2 doped ZnO-Bi2O3-B2O3 glasses
J. Alloy. Compd.
Study on the structure, thermal and optical properties in Cr2O3-incorporated MgO-Al2O3-SiO2-B2O3 glass
J. Non-Cryst. Solid.
Low-cost and environment-friendly ceramic foams made from lead-zinc mine tailings and red mud: foaming mechanism, physical, mechanical and chemical properties
Ceram. Int.
Crystallisation kinetics, glass forming ability and thermal stability in glassy Se100-xInx chalcogenide alloys
J. Non-Cryst. Solid.
Can glass stability parameters infer glass forming ability?
J. Non-Cryst. Solid.
A new glass-forming ability criterion for bulk metallic glasses
Acta Mater
Surface crystallization of silicate glasses: nucleation sites and kinetics
J. Non-Cryst. Solid.
Solid State 27Al NMR and FTIR study of Lanthanum Aluminosilicate glasses
J. Non-Cryst. Solid.
Structure and crystallization of B2O3-Al2O3-SiO2 glasses
Physica B
Structure and properties of calcium aluminosilicate glasses
J. Non-cryst. Solid.
Free volume and structure of Gd2O3 and Y2O3 Co-doped silicate glasses
J. Non-Cryst. Solid.
Materials development and potential applications of transparent ceramics: a review
Mat. Sci. Eng. R.
Effects of glass structure on the corrosion behavior of sodium-aluminosilicate glasses
J. Non-Cryst. Solids
The mechanism of borosilicate glass corrosion revisited
Geochim. Cosmochim. Ac.
The effect of V2O5 on alkaline earth zinc borate glasses studied by EPR and optical absorption
J. Mol. Struct.
Structural and optical properties of the lead based glasses containing iron (III) oxide
J. Non-Cryst. Solid.
Effect of CuO addition on the optical and electrical properties of sodium zinc borophosphate glasses
Phys. B Condens. Matter
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These authors contributed equally to this work and should be considered co-first authors.