Chapter 14 - Coupling Interfacial Electrochemistry with Nuclear Magnetic Resonance Spectroscopy: An Electronic Perspective
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In situ electrochemical nuclear magnetic resonance spectroscopy for electrocatalysis: Challenges and prospects
2017, Current Opinion in ElectrochemistryCitation Excerpt :In terms of unraveling molecular dynamic processes, the temperature and/or magnetic field dependence of the nuclear spin dynamics, as characterized by both the spin-lattice and spin-spin relaxation time T1 and T2 respectively, permits access to motional information over an impressive time range from ∼10−9 to 102 s. Moreover, NMR is noninvasive, applicable to almost all forms of matters (be it liquid, solid or gaseous), technically versatile for in situ measurements and imaging, and can see buried interfaces that are usually inaccessible to many other spectroscopic methods. As such, these advantageous features have continued to entice practitioners to expand its application horizon [1], including in situ measurements in the field of electrochemistry [2•–12] despite the intrinsic technical incompatibility between the conventional electrical induction detection for NMR and electrical conduction necessary for electrochemistry measurements. The initiation of in situ EC-NMR to studying Pt-based electrocatalysts and associated electrocatalysis [13–15], Figure 1a, was largely inspired by the ingenious work of Slichter and co-workers in gas–phase heterogeneous catalysis [16••,17].
A Water-Soluble Cu Complex as Molecular Catalyst for Electrocatalytic CO<inf>2</inf> Reduction on Graphene-Based Electrodes
2019, Advanced Energy MaterialsElectrochemical energy generation and storage as seen by In-Situ NMR
2017, Springer Handbooks