Journal of Photochemistry and Photobiology A: Chemistry
Spectral and photochemical behaviour of mononuclear and dinuclear α-diimine complexes of Pt(II) and Pd(II) with catechol derivatives
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Alkyl chain functionalised, cyclometalated platinum(II) complexes: Syntheses, luminescence properties and X-ray crystal structure
2016, Journal of Organometallic ChemistryCitation Excerpt :There is an ever-expanding range of suitable ligands that can be coordinated to square planar Pt(II) in a cyclometalating manner. The relative ease of design, and attempts at tuning the resultant physical properties of the complex, have led to cyclometalated platinum complexes being studied in photocatalysis [2], photooxidation (via the photogeneration of 1O2) [3], electroluminescent cells [4], luminescent bioimaging agents [5] and optical sensors [6]. Planar cyclometalated Pt(II) complexes have also recently been investigated with respect to the design of targeted agents for binding amyloid beta peptide [7], in the context of the inhibition of Zn and Cu peptide complex formation (cf. Alzheimer's disease).
Red to near-infrared organometallic phosphorescent dyes for OLED applications
2014, Journal of Organometallic ChemistryCitation Excerpt :It is believed that the efficiencies of Os-6 and Os-7 can be further improved if a lower driving voltage can be achieved. Cyclometalated Pt(II) complexes have also attracted considerable attention in the context of their PHOLED application, as they have strong spin-orbital coupling at room temperature which result in highly phosphorescent emission [79–83]. However, as compared to Ir(III) complexes, cyclometalated Pt(II) complexes display relatively lower emission efficiency and longer phosphorescence lifetime which suffer from pronounced TTA and exhibit rapidly decreased emission efficiency at high current density [84–86].
Highly-efficiency red-emitting platinum (II) complexes containing 4′-diarylamino-1-phenylisoquinoline ligands in polymer light-emitting diodes: Synthesis, structure, photoelectron and electroluminescence
2010, Dyes and PigmentsCitation Excerpt :Phosphorescent cyclometalated platinum (II) complexes have attracted considerable interest in the context of their application in the fields of optical chemosensors [1–5], photocatalysts [6–8], solar energy conversion [9–11] and organic/polymer light-emitting diodes (OLEDs/PLEDs) [12–15].
Excimer and electron transfer quenching studies of a cyclometalated platinum complex
2005, Coordination Chemistry Reviews