Elsevier

Synthetic Metals

Volume 72, Issue 1, 15 April 1995, Pages 95-98
Synthetic Metals

Article
Oxidative polymerization of poly(2-(N-pyrrolyl)ethyl methacrylate) with iron chloride

https://doi.org/10.1016/0379-6779(94)02323-QGet rights and content

Abstract

Polymers 2 containing pyrrole in the side group were synthesized by radical polymerization of 2-(N-pyrrolyl)ethyl methacrylate 1 (PEMA). The PEMA units were coupled by oxidation with iron chloride in nitromethane. The polymers reached conductivities about 5 × 10−5 S/cm upon doping with iodine. The polymers were further characterized using 1H NMR, IR, gel permeation chromatography and thermogravimetric analysis.

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