Regular paperThe redox behaviour of ferrocenyl alcohols and ferrocenediyl-diols: crystal and molecular structure of ferrocenyl(2-furyl) phenylmethanol☆
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From ferrocenyl selenoesters to diferrocenyl methanols
2018, Journal of Organometallic ChemistryCitation Excerpt :During the electrochemical investigations of the diferrocenyl methanol compounds 4a and 4b two reversible well-separated one-electron redox processes could be detected for the ferrocenyl substituents with a redox separation of ΔE0’ = 330 mV (4a) and 367 mV (4b) (Table 3 and Fig. 6). This indicates a better stabilization of the positive charge within the diferrocenyl methanol systems in presence of a more electron-rich substituent with increased aromaticity at the aliphatic carbon atom [39,47,48]. Similar observations were made during the electrochemical study of diferrocenyl methanol in comparison with its aryl and alkyl functionalized derivatives [39,47,48].
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1997, Journal of Organometallic ChemistryThe redox behaviour of some bis-ferrocenyl compounds: Crystal and molecular structures of diferrocenylmethane and diferrocenylmethanol
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Part IX of the series “The redox behaviour of ferrocene molecules”. For Part VIII, see Ref. [1].