Darstellung und Molekülstruktur des (μ-Alkylidenamido)titanocenkomplexes [(C5H5)2TiCl]2[μ-{NC(CH2C6H5)C(CH2C6H5)N}]
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Formation of [(CO)(HCCH)Tp'W=NCH(CH<inf>3</inf>)CH(CH<inf>3</inf>)N=WTp'(HCCH)(CO)][I<inf>3</inf>]<inf>2</inf> by oxidation of Tp'W(CO)(HCCH)(NCHCH<inf>3</inf>) and radical dimerization
2017, Journal of Organometallic ChemistryCitation Excerpt :For nitriles the metallacyclic products are usually formed either by the coupling of two nitrogen bound nitriles through their beta carbons, forming 5-membered metallacycles [23,24], or by the addition of alkynes [24], or even CO2 [23], which insert to create analogous products. Bridged complexes have been formed using zirconium [25], titanium [26,27], niobium [28], tantalum [28–30], molybdenum [31,32], tungsten [33,34], iridium [35] and germanium, and they reflect either the formation of diazavinylidene bridges [25,31,32,35–37] (Scheme 2(a)) or enediimido bridges [26,29,30,33,38] (Scheme 2(b)). In the case of the diazavinylidenes a new C-C single bond is formed.
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