Interaction of unequal double layers at constant charge
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2023, Journal of Membrane ScienceCitation Excerpt :Although a modified P–B equation under the assumption of constant charge has been developed [19], the repulsion between two surfaces at close approach is still overestimated as the linearization is based on a simplification of the Taylor series whereby only the first two terms are considered [20]. Notably, it has been highlighted that neither constant potential nor constant charge is a valid assumption when calculating EL interaction, as neither is likely correct in practical applications [16]. Correspondingly, the linear superposition approximation (LSA) was conceived [10,11,16], which gives intermediate results between the constant charge and constant potential scenarios.
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