Application of the SPE method to organic electrochemistry—VII. The reduction of nitrobenzene on a modified Pt-nafion
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Cited by (55)
Membrane electrolysis—History, current status and perspective
2016, Electrochimica ActaCitation Excerpt :In an alkaline environment this spans a very broad spectrum of materials, ranging from the above-mentioned spinel and perovskite structure oxides to carbon materials, like graphene and graphene oxide. Additionally, organic electrosynthesis offers significant room for further exploitation of membrane electrolysis [136–140,274,275]. It is typically used for high value-added synthesis with small production capacities.
In situ FT-IR spectroelectrochemical study of the reduction of 1,4-dinitrobenzene in room-temperature ionic liquids
2016, Journal of Electroanalytical ChemistryCitation Excerpt :Thus, they have been used in many electrochemical processes. The electrochemical redox of nitro compounds has been researched extensively in the past years [10–19]. As is known to all, electrochemical reduction of nitro compounds is a complicated process.
PERFORMANCE ASSESSMENT of A POLYMER ELECTROLYTE MEMBRANE ELECTROCHEMICAL REACTOR under ALKALINE CONDITIONS - A CASE STUDY with the ELECTROOXIDATION of ALCOHOLS
2016, Electrochimica ActaCitation Excerpt :In this regard, the concept of Polymer Electrolyte Membrane Electrochemical Reactor (PEMER) has been recently introduced in organic electrosynthesis, e.g. for the N-acetyl-L-cysteine production from the electroreduction of N,N-diacetyl-L-cysteine [5] and the synthesis of 1-phenylethanol from the electroreduction of acetophenone [6,7] under acidic conditions. Moreover, pioneering work performed by Ogumi and co-workers on the electrochemical hydrogenation of olefinic double bonds [8] and the reduction of nitrobenzene [9] was performed using a Nafion membrane-based SPE, within a similar configuration to PEMER, in which the product purification operations were then reduced. To the best of our knowledge and from a synthetic point of view, there are few works dealing with the electrooxidation of alcohols within a configuration similar to PEMER and/or filter-press electrochemical cell under alkaline conditions [10–12].
Tungsten carbide-supported Pd electrocatalysts for triglyceride hydrogenation in a solid polymer electrolyte reactor
2012, Electrochemistry CommunicationsCitation Excerpt :Pintauro and coworkers carried out this reaction with noble metal catalysts in SPE reactors, and reported high hydrogenation rates and better product selectivities than conventional thermocatalytic reactors, at the same extents of hydrogenation [14–16]. SPE reactors are also used for the chloralkali process [1] and in fuel cell applications [17], and have been investigated for the production of chemicals such as benzene and allyl alcohol [18,19]. These types of reactors allow facile transport of ionic species (e.g., protons) to the catalyst surface through the membrane under an applied potential.
Cogeneration of cyclohexylamine and electrical power using PEM fuel cell reactor
2001, Electrochemistry Communications