Elsevier

Chemical Physics Letters

Volume 26, Issue 2, 15 May 1974, Pages 163-166
Chemical Physics Letters

Raman spectra of pyridine adsorbed at a silver electrode

https://doi.org/10.1016/0009-2614(74)85388-1Get rights and content

Abstract

Raman spectroscopy has been employed for the first time to study the role of adsorption at electrodes. It has been possible to distinguish two types of pyridine adsorption at a silver electrode. The variation in intensity and frequency of some of the bands with potential in the region of the point of zero charge has given further evidence as to the structure of the electrical double layer; it is shown that the interaction of adsorbed pyridine and water must be taken into account.

References (12)

  • A.H. Reed et al.

    Electrochim. Acta

    (1970)
  • R.G. Barradas et al.

    J. Electroanal. Chem.

    (1963)
  • A.N. Frumkin

    Z. Physik

    (1926)
  • W.R. Heineman et al.

    Anal. Chem.

    (1968)
  • M. Fleischmann et al.

    J. Chem. Soc. Chem. Commun.

    (1973)
  • A.J. McQuillan, Faraday Discussion No. 56, to be...
There are more references available in the full text version of this article.

Cited by (0)

View full text