Elsevier

Carbon

Volume 29, Issue 7, 1991, Pages 817-819
Carbon

Regular article
Surface modification of ultradispersed diamonds

https://doi.org/10.1016/0008-6223(91)90155-CGet rights and content

Abstract

Ultradispersed diamond samples modified by treatment with an oxidant and then with chlorine, fluorine, and hydrogen followed by interaction of the chlorinated diamond with hydrogen, water, ammonia, or methylamine are described. For the study of these samples, elemental analysis, 1RS, XRD, XPS, ESR, DTA, and titrometric methods have been used.

References (10)

  • V.L. Kuznetsov et al.

    Carbon

    (1991)
  • H.P. Boehm

    Adv. Catal.

    (1966)
  • E.P. Smirnov et al.

    Zh. Prikl. Kihm.

    (1978)
  • S.K. Gordeev et al.

    Zh. Prikl. Khim.

    (1980)
  • S.K. Gordeev et al.

    Zh. Prikl. Khim.

    (1979)
There are more references available in the full text version of this article.

Cited by (55)

  • Polymer/nanodiamond composites - a comprehensive review from synthesis and fabrication to properties and applications

    2019, Advances in Colloid and Interface Science
    Citation Excerpt :

    ND-Cl particles have been used for amine [187,192,201] and HEMA [179,202] functionalization at solution phase reactions. High temperature gas phase reaction was also used for fluorination, chlorination and hydrogenation of ND [203,204]. It was shown that fluorination of ND reduced the average particle size, removed impurities of ND surface and made it suitable for preparation of polymer composites.

  • Network structure and mechanical properties of polydimethylsiloxane filled with nanodiamond – Effect of degree of silanization of nanodiamond

    2017, Composites Science and Technology
    Citation Excerpt :

    Surface treatment of ND is an effective approach to prevent ND agglomeration and improve filler-polymer interaction [17]. In literature, different surface functionalization of ND have been reported such as functionalization with fluorine [18], mineral acids [19] and acrylates [20]. The interest in ND-filled polymer nanocomposites has progressively increased, especially in biomedical applications [21], protective coatings [22] and reinforced polymeric composites [23].

  • Silane functionalization of nanodiamond for polymer nanocomposites-effect of degree of silanization

    2016, Colloids and Surfaces A: Physicochemical and Engineering Aspects
  • Chromatographic performance of synthetic polycrystalline diamond as a stationary phase in normal phase high performance liquid chromatography

    2015, Journal of Chromatography A
    Citation Excerpt :

    Carbonyl related stretches νCO from carboxylic groups with characteristic band at 1730 cm−1 are also clearly present in both samples [38]. The intensity of the broad absorption band 1000 and 1100 cm−1, indicating the presence of silica in diamond, is decreased for the purified sample as earlier observed by Loktev et al. [39]. Two sharp bands at 1385 cm−1 and 2426 cm−1, which presented only in original HPHT diamond can likely be attributed to the presence of some admixture or further unknown anticaking reagent.

View all citing articles on Scopus
View full text