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C-dots/Mn3O4 nanocomposite as an oxidase nanozyme for colorimetric determination of ferrous ion

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Abstract

At first, C-dots/manganese oxide nanocomposite was synthesized chemically. The presence of Mn3O4 nanostructures and C-dots in the synthesized nanocomposite was confirmed by using of XRD, EDS, FTIR and TEM. The proposed method for synthesis is easy and cheap. The Mn3O4/C-dots nanocomposite shows oxidase-like activity, which is higher than oxidase-like activity of Mn3O4 nanoparticles. In this manner, detection of ferrous ion was possible by using of a competitive reaction between 3,3′,5,5′-tetramethylbenzidine and Fe2+ ion in the presence of the synthesized nanocomposite. So, a sensitive and selective colorimetric sensor for determination of Fe2+ ion was introduced. The linear range and detection limit for determination of Fe2+ ion were obtained as 0.03–0.83 μM and 0.03 μM, respectively.

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Acknowledgements

The authors wish to acknowledge the support of this work by Islamic Azad University, Shiraz Branch.

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Authors and Affiliations

  1. Department of Chemistry, Shiraz Branch, Islamic Azad University, Shiraz, Iran

    Fatemeh Honarasa, Fatemeh Peyravi & Hesam Amirian

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  1. Fatemeh Honarasa
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  2. Fatemeh Peyravi
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  3. Hesam Amirian
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Correspondence to Fatemeh Honarasa.

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Honarasa, F., Peyravi, F. & Amirian, H. C-dots/Mn3O4 nanocomposite as an oxidase nanozyme for colorimetric determination of ferrous ion. J IRAN CHEM SOC 17, 507–512 (2020). https://doi.org/10.1007/s13738-019-01787-z

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