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Synthesis and Properties of Self-healing Metallopolymers with 5-Vinyltetrazole Units and Zn(II)

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Abstract

The development of reversible and efficient self-healing materials symbolizes an emerging and challenging task in intelligent materials science. In this paper, a facile one-pot and two-step methodology was developed for the preparation of polyacrylonitrile-r-poly(butyl acrylate) (PAN-r-PnBA) and its subsequent modification. Zinc chloride (ZnCl2) was used as a catalyst to modify cyano groups and generate tetrazole groups of PAN-r-PnBA. Simultaneously, ZnCl2 effectively coordinates with the generated tetrazole group for highly self-healing performance. It was demonstrated that the metallopolymers (MPs) exhibited excellent self-healing properties at ambient temperature. The prepared tetrazole-based MPs can be used as a wide range of self-healing materials.

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Authors and Affiliations

  1. School of Chemistry and Materials Science, Key Laboratory of High Performance and Functional Polymer in the Universities of Shandong Province, Ludong University, Yantai, 264025, P. R. China

    Mifa Chen, Wenxiang Wang, Hou Chen, Liangjiu Bai, Zhongxin Xue, Donglei Wei, Huawei Yang & Yuzhong Niu

  2. Collaborative Innovation Center of Shandong Province for High Performance Fibers and Their Composites, Ludong University, Yantai, 264025, P. R. China

    Mifa Chen, Wenxiang Wang, Hou Chen, Liangjiu Bai, Zhongxin Xue, Donglei Wei, Huawei Yang & Yuzhong Niu

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  1. Mifa Chen
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  2. Wenxiang Wang
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  3. Hou Chen
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  4. Liangjiu Bai
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  8. Yuzhong Niu
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Correspondence to Hou Chen or Liangjiu Bai.

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Acknowledgments: The financial was supported by the National Natural Science Foundation of China (Nos. 51773086, 51573075 and 21501087), the Natural Science Foundation of Shandong Province (Nos. ZR2018BB027 and ZR2018ZC0946), the Project of Shandong Province Higher Educational Science and Technology Program (Nos. J16LC20 and J18KA080) and the Program for Scientific Research Innovation Team in Colleges and universities of Shandong Province.

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Chen, M., Wang, W., Chen, H. et al. Synthesis and Properties of Self-healing Metallopolymers with 5-Vinyltetrazole Units and Zn(II). Macromol. Res. 27, 96–104 (2019). https://doi.org/10.1007/s13233-019-7032-5

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