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The hydrogeochemical characterization of groundwater in Gafsa-Sidi Boubaker region (Southwestern Tunisia)

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Abstract

Gafsa region is one of the most productive artesian basins in Southern Tunisia. It is located in the southwestern part of the country, and its groundwater resources are developed for water supply and irrigation. Proper understanding of the geochemical evolution of groundwater is important for sustainable development of water resources in this region. A hydrogeochemical survey was conducted on the Plio-Quaternary shallow and on the Complex Terminal aquifers system using major (Ca, Mg, Na, SO4, Cl, NO3 and HCO3) and minor (Sr) elements, in order to evaluate the groundwater chemistry patterns and the main mineralization processes occurring in this system. Hydrochemical and isotopic data were used in conjunction with hydrogeological characteristics to investigate the groundwater composition in these aquifers. It has been demonstrated that groundwaters acquire their mineralization principally by water–rock interaction, i.e. dissolution of evaporites (halite/gypsum, pyrite, etc.) and return flow of irrigation waters, and by anthropogenic activities due to the use of nitrogen (N) fertilizers–pesticides in agriculture. The isotopic study of “stable isotopes, radiocarbon and tritium” (Yermani 2002) shows that a paleoclimatic recharge is corroborated by the relatively low carbon-14 activities (5–25.3%) of the referred groundwater group samples, which were interpreted as recharge occurring during the late Pleistocene and the early Holocene periods. The water feedings of these aquifers are mainly provided by infiltration of precipitations, infiltration of irrigation water, lateral feeding from Cretaceous relieves from the South and the North and along recent and fossil drainage networks that constitute major freshwater sources in groundwater tables (Hamed et al., J Environ Protect 1:466–474, 2010a).

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References

  • Abidi B (2007) Caractérisation hydrogéologique, géochimique et isotopique des systèmes aquifères du synclinal de Tamerza et de la plaine de Chott El Gharsa (Sud Ouest de la Tunisie).Thèse .Doc. Fac. Des sciences de Sfax

  • Ahmadi R, Ouali J, Mercier E, Mansy JL (2006) The geomorphologic responses to hinge migration in the fault-related folds in the Southern Tunisian Atlas. J Struct Geol 28:721–728

    Article  Google Scholar 

  • Ben Moussa A, Bel Haj Salem S, Zouari K, Jlassi F (2010) Hydrochemical and isotopic investigation of the groundwater composition of an alluvial aquifer, Cap Bon Peninsula, Tunisia Carbonates Evaporites. Earth Env Sci 25:161–176. doi:10.1007/s13146-010-0020-7

    Google Scholar 

  • Brondi M, Fidelibus MD, Gragnani R, Tulipano L (1983) Hydrochemical study and distribution of some trace elements in the most important coastal springs and groundwater of the Apulian region (southern Italy). Geologia Applicatta et Idrogeologia 17(2):65–80

    Google Scholar 

  • Bohike JK, Smith RL, Hannon JE (2007) Isotopic analysis of N and O in nitrite and 383 nitrate by sequential selective bacterial reduction to N2O. Anal Chem 79(384):5888–5895

    Google Scholar 

  • Castany G (1982) Bassin sédimentaire du Sahara septentrional (Algérie-Tunisie)—Aquifères du Continental intercalaire et du Complexe Terminal. Bulletin Bureau Recherches Géologiques Minières (BRGM). Série 2. 3. 127–147

  • Celle H (2000) Caractérisation des précipitations sur le pourtour de la méditerranée occidentale. Approche isotopique et chimique. [Rainfall characterization on the western Mediterranean rim: an isotopic and chemical approach]. Ph.D. thesis, Universite´ d’Avignon et Pays-de-Vaucluse

  • Celle-Jeanton H, Travi Y, Blavoux B (2001) Isotopic typology of the precipitation in the western Mediterranean region at three different time scales. Geophys Res Lett 28(7):1215–1218

    Article  Google Scholar 

  • Clark I, Fritz P (1997) Environmental isotopes in hydrogeology. Lewis Publishers, Boca Raton

    Google Scholar 

  • Colpen TB, Wildman J, Chen J (1991) Improvement in the gaseous hydrogen-water equilibration technique for hydrogen isotopes ration analysis. Anal Chem 63:910–912

    Article  Google Scholar 

  • Coplen TB (1996) New guidelines for reporting stable hydrogen, carbon, and oxygen isotope-ratio data. Geochim Cosmochim Acta 60:3359–3360

    Article  Google Scholar 

  • Coque R (1962) La Tunisie présaharienne: étude géomorphologique. Armond Colin, Paris

    Google Scholar 

  • Dassi L (2009) Use of chloride mass balance and tritium data for estimation of groundwater recharge and renewal rate in an unconfined aquifer from North Africa: a case study from Tunisia. Environmental Earth Sciences. doi:10.1007/s12665-009-0223-1

  • Dassi L, Zouari K, Faye S (2005) Identifying sources of groundwater recharge in the Merguellil basin (Tunisia) using isotopic methods: implication of dam reservoir water accounting. Eviron Geol 49:114–123

    Article  Google Scholar 

  • DGRE (Direction Générale des Ressources en Eau) (2010) Annuaire de l’exploitation des nappes de la Tunisie. DGRE, Tunis

    Google Scholar 

  • Dlala M, Hfaiedh M (1993) Le séisme du 7 Novembre 1989 à Métlaoui (Tunisie Méridionale): une tectonique active en compression. CRAS 317:1297–1307

    Google Scholar 

  • Edmunds WM, Smedley PL (2000) Residence time indicators in groundwater: the East Midlands Triassic sandstone aquifer. Appl Geochem 15:737–752

    Article  Google Scholar 

  • Edmunds W, Guendouz A, Mamou A, Moulla A, Shand P, Zouari K (2003) Groundwater evolution in the Continental Intercalaire aquifer of southern Algeria and Tunisia: trace element isotopic indicators. Appl Geochem 18:805–822

    Article  Google Scholar 

  • Epstein S, Mayeda TK (1953) Variations of 18O content of waters from natural sources. Geochim Cosmochim Acta 4:213–224

    Article  Google Scholar 

  • Farhat H, Moumni L (1989) Etude hydrogéologique du basin du Gafsa-Nord. DGRE, Tunis, p 159

    Google Scholar 

  • Faye S, Maloszewskib P, Stichlerb W, Trimbornb P, Fayea SC, Gaye ChB (2005) Groundwater salinization in the Saloum (Senegal) delta aquifer: minor elements and isotopic indicators. Sci Total Environ 343:243–259

    Article  Google Scholar 

  • Fontes JC (1971) Un ensemble destiné à la mesure de l’activité du radiocarbone naturel par scintillation liquide [A unit intended for the measurement of the activity of natural radiocarbon by liquid scintillation]. Rev Geogr Phys Géol Dyn 13(1):67–86

    Google Scholar 

  • Fontes JC, Coque R, Dever L, Filly A, Mamou A (1983) Paléohydrologie isotopique de l´wadi el Akarit (Sud Tunisien) au Pléistocène et à l´Holocène. Pal 43:41–61

    Google Scholar 

  • Gautier M (1953) Les chotts, machines evaporitives complexes. Centre National de la Recherche Scientifique (CNRS). Colloq Int 35:317–325

    Google Scholar 

  • Geyh MA (2000) An overview of 14C analysis in the study of groundwater. Radiocarbon 42(1):99–114

    Google Scholar 

  • Gi-Tak C, Kangjoo K, Seong T, Kyoung H, Soon O, Byoung Y, Hyoung S, Chul W (2004) Hydrogeochemistry of alluvial groundwaters in an agricultural area: an implication for groundwater contamination susceptibility. Chemosphere 55:369–378

    Article  Google Scholar 

  • Gosselin DC, Harvey FE, Frost C, Stotler R, Macfarlane PA (2004) Strontium isotope geochemistry of groundwater in the central part of Dakota (Great Plains) aquifer, USA. Appl Geochem 19:359–377

    Article  Google Scholar 

  • Guendouz A, Moulla AS, Edmunds WM, Zouari K, Shand P, Mamou A (2003) Hydrogeochemical and isotopic evolution of water in the Complex Terminal aquifer in the Algerian Sahara. J Hydrol 11:483–495

    Google Scholar 

  • Hamed Y (2009a) Caractérisation hydrogéologique, hydrochimique et isotopique du système aquifère de Moularés-Tamerza. Ph.D. thesis, University of Sfax, pp 280

  • Hamed Y (2009b) Découvrir le Sud Ouest Tunisien “Gafsa et Tozeur” Livre, ISBN:978-9973-0-0671-4

  • Hamed Y, Dassi L, Ahmadi R, Ben Dhia H (2008) Geochemical and isotopic study of the multilayer aquifer system in the Moulares-Redayef basin, southern Tunisia. Hydrol Sci J 53(5):1241–1252

    Article  Google Scholar 

  • Hamed Y, Zairi M, Ali W, Ben Dhia H (2010a) Estimation of residence times and recharge area of groundwater in the Moulares mining basin by using carbon and oxygen isotopes (South Western Tunisia). J Environ Protect 1:466–474

    Article  Google Scholar 

  • Hamed Y, Dassi L, Tarki M, Ahmadi R, Mehdi K, Ben Dhia H (2010b) Groundwater origins and mixing pattern in the multilayer aquifer system of the Gafsa-south mining district: a chemical and isotopic approach. Environ Earth Sci 63:1355–1368

    Article  Google Scholar 

  • Henchiri M, Slim-S’Himi N (2006) Silification of sulphate evaporites and their carbonate replacements in Eocene marine sediments, Tunisia: two diagenic trends. Sedimentology 53:1135–1159

    Article  Google Scholar 

  • Kamel S, Dassi L, Zouari K, Abidi B (2005) Geochimical and isotopic investigation of the aquifer system in the Djerid-Nefzaoua basin, southern Tunisia. Eviron Geol 49:159–170

    Article  Google Scholar 

  • Kamel S, Hamed Y, Chkir N, Zouari K (2007) The Hydro-geochemical characterization of groundwaters in Tunisian Chott’s region. Eviron Geol. doi:10.1007/s00254-007-0867-7

  • Lucas LL, Unterweger MP (2000) Comprehensive review and critical evaluation of the half-life of tritium. J Res Natl Inst Stand Technol 105(4):541–549

    Article  Google Scholar 

  • Mamou A (1989) Caractéristiques et évaluation et gestion des ressources en eau du Sud tunisien. Thèse Doctorat. Univ. de Paris Sud, France

  • Mann AW (1983) Hydrogeochemistry and weathering on the Yilgarn Block, Western Australia—ferrolysis and heavy metals in continental brines. Geochim Cosmochim Acta 47:181–190

    Article  Google Scholar 

  • Melanie JL, Marshall JD (2004) Palaeoclimate interpretation of stable isotope data from lake sediment archives. Quat Sci Rev 23:811–831

    Article  Google Scholar 

  • Meybeck M (1984) Les fleuves et le cycle géochimique des éléments. Ph.D. thesis, University Paris VI, France

  • Morgan-Jones M, Eggboro MD (1981) The hydrogeochemical of the Jurassic limestones in Gloucestershire, England. Q J Eng Geol Hydrogeol (Lond) 14:25–29

    Article  Google Scholar 

  • OSS (2003) Système aquifère du Sahara septentrional. Observatoire du Sahara et du Sahel. Tech. Rep. 9973–856, Tunis

  • Ouda B (2000) Paléohydrologie isotopique du basin de Meknassi (Tunisie centrale) pendant le quaternaire recent [Paleohyrology isotope in the Meknassi (central Tunisia) basin during the recent quaternary]. Ph.D. thesis, Tunis II University, Tunis, Tunisia

  • Piper AM (1944) A graphic procedure in the geochemical interpretation of water-analyses. Trans Am Geophys Union 25:914–923

    Article  Google Scholar 

  • Romanek CS, Grossman EL, Morse JW (1992) Carbon isotopes fractionation in synthetic aragonite and calcite: effects of temperature and precipitation rate. Geochim Cosmochim Acta 56:419–430

    Article  Google Scholar 

  • Solomon DK (2000) 3H and 3He, chapter 13, pp 397–424. In: Cook PG, Herczeg AL (eds) Environmental tracers in subsurface hydrology. Kluwer, Boston, 529 p

  • Stigter TY, Carvalho AM, Ribeiro L, Reis E (2006) A impact of the shift from groundwater to surface water irrigation on aquifer dynamics and hydrochemistry in a semi-arid region in the south of Portugal. Agric Water Manag 85:121–132

    Article  Google Scholar 

  • Swezey CS (1997) Climatic and tectonic controls on Quaternary eolian sedimentary sequences of The Chott Rharsa Basin, southern Tunisia: Ph.D. dissertation, The University of Texas at Austin (USA)

  • Swezey CS (2003) The role of climate in the creation and destruction of continental stratigraphic records: an example from the northern margin of the Sahara Desert. Climate controls on stratigraphy. SEPM Spec Publ 77:207–225

    Google Scholar 

  • UNESCO (1972) Etude des ressources en eau du Sahara Septentrional. Tech Rep 6:44

    Google Scholar 

  • Vogel JC (1993) Variability of carbon isotope fractionation during photosynthesis. In: Ehleringer JR, Hall AE, Farquhar GD (eds) Stable isotopes and plant carbon–water relations. Academic, San Diego, pp 29–46

    Chapter  Google Scholar 

  • WHO (2006) World Health Organization. Guidelines for drinking water quality, 3rd edn, incorporating first addendum. Available at http://www.who.int/water_sanitation_health/dwq/gdwq3rev/en/index.html

  • Yermani M (2002) Contribution à l’étude du fonctionnement hydrodynamique du système aquifère de Gafsa Nord (Tunisie centrale). Thèse Doctorat Univ. de Tunis II, Tunisia

  • Yermani M, Zouari K, Michelot JL, Mamou A, Moumni L (2003) Approche géochimique du fonctionnement de la nappe profonde de Gafsa Nord (Tunisie centrale)/Geochemical approach to the functioning of the Gafsa North deep aquifer (central Tunisia). Hydrol Sci J 48(1):95–108

    Article  Google Scholar 

  • Zargouni F (1985) Tectonique de l’Atlas méridional de Tunisie, évolution géométrique et cinématique des structures en zones de cisaillement. Univ. Louis Pasteur Strasbourg, France

    Google Scholar 

  • Zouari K, Chkir N, Ouda B (2003) Palaeoclimatic variation in Maknassi basin (central Tunisia) during Holocene period using pluridisplinary approaches. IAEA, Vienna. CN 80–28

Download references

Acknowledgements

The author gratefully acknowledges the contributions of the staff members of Gafsa Water Resources Division/Agriculture Ministry and the members of phosphate Company of Gafsa “CPG”, for their help during field work. We also thank the technical staff at the Laboratory of the International Agency of Atomic Energy and the Department of Earth Sciences, Water, Energy and Environmental Laboratory (L3E) of the National Engineering School of Sfax (ENIS-Tunisia) for their help and assistance during Laboratory analyses. The author greatly appreciates the constructive and thoughtful comments of the anonymous reviewer.

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Hamed, Y. The hydrogeochemical characterization of groundwater in Gafsa-Sidi Boubaker region (Southwestern Tunisia). Arab J Geosci 6, 697–710 (2013). https://doi.org/10.1007/s12517-011-0393-5

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