Skip to main content

Advertisement

SpringerLink
Log in

Manganese dioxide nanoparticles: synthesis, application and challenges

  • Published:
Bulletin of Materials Science Aims and scope Submit manuscript

Abstract

In recent days, manganese oxide nanoparticles (MnO2 NPs) have intrigued material science researches extensively due to its wide range of applications. They are widely used in energy storage devices (lithium-ion batteries, capacitors), catalysts, adsorbent, sensors and imaging, therapeutic activity, etc. Since they hold a lot of distinguished potentials, a robust protocol for cheap, stable, biocompatible and eco-friendly MnO2 NPs is necessary. They can be categorized into different phases like α, β, δ and others. Thus, owing to their peculiar character, they could be utilized for various purposes depending on the mode of action and applications. Hence, this review has summarized conventional methods, such as hydrothermal, sol–gel, oxidation–reduction used for the generation of MnO2 NPs. Likewise, morphological characterization by various spectroscopic techniques also outlined. It is found that the particular method of generation of MnO2 NPs is useful for a specific phase.

Graphic Abstract

Graphical representation of manganese dioxide nanoparticles: synthesis and application

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Figure 1

Similar content being viewed by others

References

  1. Schmid G 2006 Nanoparticles: from theory to applications 2nd edn (Wiley-VCH)

  2. Burda C, Chen X, Narayanan R and El-Sayed M A 2005 Chem. Rev. 105 1025

    CAS  Google Scholar 

  3. Najafpour M M and Allakhverdiev S I 2012 Int. J. Hydrog. Energy 37 8753

    CAS  Google Scholar 

  4. Lin T, Yu L, Sun M, Cheng G, Lan B and Fu Z 2016 Chem. Eng. J. 286 114

    CAS  Google Scholar 

  5. Štengl V, Králová D, Opluštil F and Němec T 2012 Micropor. Mesopor. Mater. 156 224

    Google Scholar 

  6. Nikam A V, Prasad B L V and Kulkarni A A 2018 CrystEngComm 20 5091

    CAS  Google Scholar 

  7. Qi S Y, Feng J, Yan J, Hou X Y and Zhang M L 2008 Chin. J. Nonferrous Met. 18 113

    CAS  Google Scholar 

  8. Zhang H T, Chen X H, Zhang J H, Wang G Y, Zhang S Y, Long Y Z et al 2005 J. Cryst. Growth 280 292

    CAS  Google Scholar 

  9. Ching S, Roark J L, Duan N and Suib S L 1997 Chem. Mater. 9 750

    CAS  Google Scholar 

  10. Yin H, Dai X, Zhu M, Li F, Feng X and Liu F 2015 J. Hazard. Mater. 296 221

    CAS  Google Scholar 

  11. Shaker K and Abdalsalm A H 2018 Eng. Tech. J. 36 946

    Google Scholar 

  12. Sinha A, Nand V, Raj B and Kumar S 2011 J. Hazard. Mater. 192 620

  13. Zhang X, Sun X, Zhang H, Zhang D and Ma Y 2013 Electrochim. Acta 87 637

    Google Scholar 

  14. Ai Z, Zhang L, Kong F, Liu H, Xing W and Qiu J 2008 Mater. Chem. Phys. 111 162

    CAS  Google Scholar 

  15. Abulizi A, Yang G H, Okitsu K and Zhu J J 2014 Ultrason. Sonochem. 21 51629

    Google Scholar 

  16. Benbow E M, Kelly S P, Zhao L, Reutenauer J W and Suib S L 2011 J. Phys. Chem. C 115 22009

    CAS  Google Scholar 

  17. Liu Z, Xu K, Sun H and Yin S 2015 Small 11 20182

    Google Scholar 

  18. Robinson D M, Go Y B, Mui M, Gardner G, Zhang Z, Mastrogiovanni D et al 2013 J. Am. Chem. Soc. 135 93494

    Google Scholar 

  19. Chakrabarti S, Dutta B K and Apak R 2009 Water Sci. Technol. 60 3017

    CAS  Google Scholar 

  20. Liao X, Zhang C, Liu Y, Luo Y, Wu S, Yuan S et al 2016 Chemosphere 150 90

    CAS  Google Scholar 

  21. Shaban M, Abukhadra M R, Ibrahim S S and Shahien M G 2017 Appl. Water Sci. 7 4743

    CAS  Google Scholar 

  22. Sivaraj D and Vijayalakshmi K 2017 Mater. Sci. Eng. 81 469

    CAS  Google Scholar 

  23. Krishnaraj C, Ji B J, Harper S L and Yun S I 2016 Biopro. Biosyst. Eng. 39 759

    CAS  Google Scholar 

  24. Siddiqui S I, Manzoor O, Mohsin M and Chaudhry S A 2018 Environ. Res. 171 32018

    Google Scholar 

  25. Dong J, Hou Z, Zhao Q and Yang Q 2019 E3S Web. Conf. 03002 1

    Google Scholar 

  26. Julien C, Mauger A, Vijh A and Zaghib K (eds) 2016 Lithium batteries: science and technology (Switzerland: Springer)

    Google Scholar 

  27. Zhai L, Wang W, Yu C, Wang P and Mao Y 2014 Anal. Chem. 86 12206

    CAS  Google Scholar 

  28. Luo J, Zhu H T, Fan H M, Liang J K, Shi H L, Rao G H et al 2008 J. Phys. Chem. 112 12594

    CAS  Google Scholar 

  29. Zheng X, Sun D, Fan S, Yu W, Fan H, Cao C et al 2005 J. Phys. Chem. 109 16439

    CAS  Google Scholar 

  30. Sugantha M, Ramakrishnan P A, Hermann A M and Ginley D S 2003 Int. J. Hydrog. Energy 28 597

    CAS  Google Scholar 

  31. Cui H J, Huang H Z, Fu M L, Yuan B L and Pearl W 2011 Catal. Commun. 12 1339

    CAS  Google Scholar 

  32. Wang X and Li Y 2002 J. Am. Chem. Soc. 124 2880

    CAS  Google Scholar 

  33. Wei M, Konishi Y, Zhou H, Sugihara H and Arakawa H 2005 Nanotechnology 16 245

    CAS  Google Scholar 

  34. Yuan Z Y, Ren T Z, Du G H and Su B L 2005 Appl. Phys. A: Mater. Sci. Process. 804 743

    Google Scholar 

  35. Sun P, Yi H, Peng T, Jing Y, Wang R, Wang H et al 2017 J. Power Sources 341 27

    CAS  Google Scholar 

  36. Jana S, Pande S, Sinha A K, Sarkar S, Pradhan M, Basu M et al 2009 J. Phys. Chem. 1134 1386

    Google Scholar 

  37. Hashem A M, Abdel-Ghany A E, El-Tawil R, Bhaskar A, Hunzinger B, Ehrenberg H et al 2016 Ionics 22 2263

    CAS  Google Scholar 

  38. Song X C, Zhao Y and Zheng Y F 2007 Cryst. Growth Des. 7 159

    CAS  Google Scholar 

  39. Ragupathy P, Vasan H N and Munichandraiah N 2007 J. Electrochem. Soc. 155 34

    Google Scholar 

  40. Julien C M and Mauger A 2017 Nanomaterials 711 1

    Google Scholar 

  41. Brock S L, Duan N, Tian Z R, Giraldo O, Zhou H and Suib S L 1998 Chem. Mater. 10 2619

    CAS  Google Scholar 

  42. Byrappa K and Adschiri T 2007 Prog. Cryst. Growth Charact. Mater. 53 117

    CAS  Google Scholar 

  43. Wang X and Li Y 2003 Chem. Eur. J. 9 300

    Google Scholar 

  44. Cao G, Su L, Zhang X and Li H 2010 Mater. Res. Bull. 45 425

    CAS  Google Scholar 

  45. Cheng G, Yu L, Lan B, Sun M, Lin T, Fu Z et al 2016 Mater. Res. Bull. 75 17

    Google Scholar 

  46. Deng J M G, Feng Y H, Fang Q and Chen Y F 2009 Funct. Mater. Dev. 15 503

    Google Scholar 

  47. Lan B, Zheng X, Cheng G, Han J, Li W, Sun M et al 2018 Eletcrochim. Acta 283 459

    CAS  Google Scholar 

  48. Xu M, Kong L, Zhou W and Li H 2007 J. Phys. Chem. 111 9141

    Google Scholar 

  49. Ma R, Bando Y, Zhang L and Sasaki T 2004 Adv. Mater. 16 918

    CAS  Google Scholar 

  50. Meng Y, Song W, Huang H, Ren Z, Chen S Y and Suib S L 2014 J. Am. Chem. Soc. 136 11452

    CAS  Google Scholar 

  51. Pahalagedara L R, Dharmarathna S, King’ondu C K, Pahalagedara M N, Meng Y T, Kuo C H et al 2014 J. Phys. Chem. 118 20363

  52. Wang J, Li J, Jiang C, Zhou P, Zhang P and Yu J 2017 Appl. Catal. B: Environ. 204 147

    CAS  Google Scholar 

  53. Hashem A M, Abuzeid H M, Abdel-Latif A M, Abbas H M, Ehrenberg H, Indris S et al 2013 ECS Trans. 50 125

    Google Scholar 

  54. Tang N, Tian X, Yang C, Pi Z and Han Q 2010 J. Phys. Chem. Solids 71 258

    CAS  Google Scholar 

  55. Li B, Rong G, Xie Y, Huang L and Feng C 2006 Inorg. Chem. 45 6404

    CAS  Google Scholar 

  56. Yang L, Zhu Y and Cheng G 2007 Mater. Res. Bull. 42 159

    CAS  Google Scholar 

  57. Kaabi N, Chouchene B, Mabrouk W, Matoussi F, Selmane E and Hmida B H 2018 Solid State Ion. 325 74

    CAS  Google Scholar 

  58. Selvakumar S, Nuns N, Trentesaux M, Batra V S, Giraudon J M and Lamonier J F 2018 Appl. Catal. B: Environ. 223 192

    CAS  Google Scholar 

  59. Bach S, Henry M, Baffier N and Livage J 1990 J. Solid State Chem. 88 325

    CAS  Google Scholar 

  60. Tang W, Shan X, Li S, Liu H, Wu X and Chen Y 2014 Mater. Lett. 132 317

    CAS  Google Scholar 

  61. Ching S, Petrovay D J, Jorgensen M L and Suib S L 1997 Inorg. Chem. 36 883

    CAS  Google Scholar 

  62. Ching S, Landrigan J A, Jorgensen M L, Duan N and Suib S L 1995 Chem. Mater. 7 1604

    CAS  Google Scholar 

  63. Ching S, Welch E J, Hughes S M, Bahadoor A B F and Suib S L 2002 J. Nanomater. 8 1292

    Google Scholar 

  64. Oaki Y and Imai H 2007 Angew. Chem. Int. Ed. 46 4951

    CAS  Google Scholar 

  65. Feng Q, Liu L and Yanagisawa K 2000 J. Mater. Sci. Lett. 19 1567

    CAS  Google Scholar 

  66. Chen S, Zhu J, Han Q, Zheng Z, Yang Y and Wang X 2009 Cryst. Growth Des. 9 4356

    CAS  Google Scholar 

  67. Kanha P and Saengkwamsawang P 2017 Inorg. Nano-Met. Chem. 1 556

    Google Scholar 

  68. Zhao B, Lu M, Wang Z, Jiao Z, Hu P, Gao Q et al 2016 J. Alloys Compd. 663 180

    CAS  Google Scholar 

  69. Feng X H, Tan W F, Liu F, Wang J B and Ruan H D 2004 Chem. Mater. 16 4330

    CAS  Google Scholar 

  70. Liu X, Fu S and Huang C 2005 Power. Tech. 154 120

    CAS  Google Scholar 

  71. Muraoka Y 1999 J. Solid State Chem. 144 136

    CAS  Google Scholar 

  72. Komaba S, Kumagai N and Chiba S 2000 Electrochim. Acta 461 31

    Google Scholar 

  73. Gaillot A C, Flot D, Drits V A, Manceau A, Burghammer M and Lanson B 2003 Chem. Mater. 15 4666

    CAS  Google Scholar 

  74. Zhiliang J, Vinod X and Jaekook M 2016 Chem. Phys. Lett. 650 64

    Google Scholar 

  75. Devatha C P and Thalla A K 2018 Micro and nano technologies (Woodhead Publishing) p 169

  76. Hoseinpour V and Ghaemi N 2018 J. Photochem. Photobiol. B: Biol. 189 234

    CAS  Google Scholar 

  77. Abuzeid H M, Hashem A M, Kaus M, Knapp M, Indris S, Ehrenberg H et al 2018 J. Alloys Compd. 746 227

    CAS  Google Scholar 

  78. Hashem A M, Abuzeid H, Kaus M, Indris S, Ehrenberg H, Mauger A et al 2018 Electrochim. Acta 262 74

    CAS  Google Scholar 

  79. Hoseinpour V, Souri M and Ghaemi N 2018 Micro Nano Lett. 13 1560

    CAS  Google Scholar 

  80. Moon S A, Salunke B K, Alkotaini B, Sathiyamoorthi E and Kim B S 2015 IET Nanobiotechnol 9 220

    Google Scholar 

  81. Sanchez-Botero L, Herrera P A and Hinestroza P J 2017 Nanomaterials 7 117

    Google Scholar 

  82. Wang X and Li Y 2002 J. Am. Chem. Soc. 124 2880

    CAS  Google Scholar 

  83. Zhou J, Yu L, Sun M, Yang S, Ye F, He J et al 2013 Ind. Eng. Chem. Res. 52 9586

    CAS  Google Scholar 

  84. Wang J, Zhang G and Zhang P 2017 J. Mater. Chem. 5 5719

    CAS  Google Scholar 

  85. Iyer A, Dutta P and Suib S 2012 J. Phys. Chem. C 11 6474

    Google Scholar 

  86. Chen X, Yan S, Wang N, Peng S, Wang C, Hong Q et al 2017 RSC Adv. 7 55734

    CAS  Google Scholar 

  87. Julien C, Massot M, Rangan S, Lemal M and Guyomard D 2002 J. Raman Spectrosc. 33 223

    CAS  Google Scholar 

  88. Julien C, Massot M, Baddour-Hadjean R, Franger S, Bach S and Pereira-Ramos J P 2003 Solid State Ion. 159 345

    CAS  Google Scholar 

  89. Tang X, Li H, Liu Z, Yang Z and Wang Z 2011 J. Power Sources 96 855

    Google Scholar 

  90. Jia Z, Wang J, Wang Y, Li B, Wang B, Qi T et al 2016 J. Mater. Sci. Technol. 32 147

    CAS  Google Scholar 

  91. Shi F, Wang F, Dai H, Dai J, Deng J, Liu Y et al 2012 Appl. Catal. A: Gen. 433 206

    Google Scholar 

  92. Zhang Y, Feng H, Wu X, Wang L, Zhang A, Xia T et al 2009 Int. J. Hydrog. Energy 34 4889

    CAS  Google Scholar 

  93. Zhao X, Hou Y, Wang Y, Yang L, Zhu L, Cao R et al 2017 RSC Adv. 7 40286

    CAS  Google Scholar 

  94. Jiang Y, Cui X, Zu L, Hu Z, Gan J, Lian H et al 2015 Nanomaterials 5 1638

    CAS  Google Scholar 

  95. Denholm P, Ela E, Kirby B and Milligan M 2010 Nat. Ren. En. Lab. Tech. Rep. 25

  96. Elmaci G, Frey C E, Kurz P and Zümreoǧlu-Karan B 2016 J. Mater. Chem. 22 8812

    Google Scholar 

  97. Iyer A, Galindo H, Sithambaram S, King’ondu C, Chen C H and Suib S L 2010 Appl. Catal. A: Gen. 375 295

  98. Ding Y, Shen X, Sithambaram S, Gomez S, Kumar R, Crisostomo V M B et al 2005 Chem. Mater. 1 5382

    Google Scholar 

  99. Ma J, Wang C and He H 2017 Appl. Catal. B: Environ. 201 503

    CAS  Google Scholar 

  100. Ramesh M, Nagaraja H S, Rao M P, Anandan S and Huang N M 2016 Mater. Lett. 172 85

    CAS  Google Scholar 

  101. Saha S and Pal A 2014 Sep. Purif. Technol. 134 26

    CAS  Google Scholar 

  102. Lambert T N, Vigil J A, White S E, Delker C J, Davis D J, Kelly M et al 2017 J. Phys. Chem. C 121 2789

    CAS  Google Scholar 

  103. Hua M, Zhang S, Pan B, Zhang W, Lv L and Zhang Q 2012 J. Hazard. Mater. 211 317

    Google Scholar 

  104. Chen H, Chu P K, He J, Hu T and Yang M 2011 J. Colloid Interf. Sci. 359 68

    CAS  Google Scholar 

  105. Tan L, Wang J, Liu Q, Sun Y, Jing X, Liu L et al 2015 J. Chem. 39 868

    CAS  Google Scholar 

  106. Le T H, Ngo T H A, Doan V T, Nguyen L M T and Le M C 2019 J. Chem., Article ID 1602752

  107. Romero P G and Sanchezb C 2005 New J. Chem. 29 57

    Google Scholar 

  108. Zhai Y, Zhai J, Zhou M and Dong S 2009 J. Mater. Chem. 19 7030

    CAS  Google Scholar 

  109. Dai Y, Lu X, McKiernan M, Lee E P, Sun Y and Xia Y 2010 J. Mater. Chem. 20 3157

    CAS  Google Scholar 

  110. Cao J, Mao Q, Shi L and Qian Y 2011 J. Mater. Chem. 21 16210

    CAS  Google Scholar 

  111. Xiao W, Zhou P, Mao X and Wang D 2015 J. Mater. Chem. A 3 8676

    CAS  Google Scholar 

  112. Bai Y H, Du Y, Xu J J and Chen H Y 2007 Electrochem. Commun. 910 2611

    Google Scholar 

  113. Dontsova E A, Zeifman Y S, Budashov I A, Eremenko A V, Kalnov S L and Kurochkin I N 2011 Sens. Actuators 1591 261

    Google Scholar 

  114. Xia C, Ning W and Lin G 2009 Sens. Actuators B Chem. 137 710

    CAS  Google Scholar 

  115. Dai Y, Huang J, Zhang H and Liu C C 2018 Sens. Actuators B Chem. 281 746

    Google Scholar 

  116. Ahn M S, Ahmad R, Yoo J Y and Hahn Y B 2018 J. Colloid Interf. Sci. 516 364

    CAS  Google Scholar 

  117. Sivaraj D and Vijayalakshmi K 2017 Mater. Sci. Eng. C 81 469

    CAS  Google Scholar 

  118. Krishnaraj C, Ji B J, Harper S L and Yun S I 2016 Bioproc. Biosyst. Eng. 39 5759

    Google Scholar 

  119. Shin J, Anisur R M, Ko M K, Im G H, Lee J H and Lee I S 2009 Angew. Chem. Int. Ed. 48 321

    CAS  Google Scholar 

  120. Tian L, Chen Q, Yi X, Chen J, Liang C, Chao Y et al 2017 Small 13

  121. Song M, Liu T, Shi C, Zhang X and Chen X 2016 ACS Nano 10 633

  122. Wang L, Chen J, Feng X, Zeng W, Liu R, Lin X et al 2016 RSC Adv. 6 65624

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Central Department of Chemistry, Tribhuvan University, Kirtipur, Kathmandu, 44618, Nepal

    Sonika Dawadi, Manita Khatri, Biplab Budhathoki, Ganesh Lamichhane & Niranjan Parajuli

  2. Department of Chemistry and Biochemistry, University of Massachusetts Dartmouth, North Dartmouth, MA, 02747, USA

    Aakash Gupta

Authors
  1. Sonika Dawadi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Aakash Gupta
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Manita Khatri
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Biplab Budhathoki
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Ganesh Lamichhane
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Niranjan Parajuli
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Niranjan Parajuli.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dawadi, S., Gupta, A., Khatri, M. et al. Manganese dioxide nanoparticles: synthesis, application and challenges. Bull Mater Sci 43, 277 (2020). https://doi.org/10.1007/s12034-020-02247-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s12034-020-02247-8

Keywords

Search

Navigation