Skip to main content
Log in

Durable UV-protective cotton fabric by deposition of multilayer TiO2 nanoparticles films on the surface

  • Published:
Journal of Coatings Technology and Research Aims and scope Submit manuscript

Abstract

Durable ultraviolet (UV)-protective cotton fabric has great application potential in outdoor cotton clothing. In this study, oppositely charged TiO2 nanoparticles were deposited onto cotton fabric through the layer-by-layer self-assembly technique, resulting in multilayer films with UV-protective properties. The mechanism of the technology has been investigated through characterization of the structure and properties using different techniques including FTIR, UV–Vis spectroscopy, and a scanning electron microscope with an energy-dispersive X-ray spectrum. The results showed that TiO2 nanoparticles distributed uniformly on the surface of cotton fibers. The TGA results indicated that the TiO2 nanoparticles deposit on cotton fabrics had little effect on the thermal stability of cotton fabrics. The tensile strength and air permeability of the cotton samples were tested by a universal material testing machine and automatic ventilation instrument. The UV protection property of cotton fabric after assembled multilayer films was measured by an ultraviolet transmittance analyzer, and the laundering experiments were carried out to determine the durability of TiO2 nanoparticles on cotton fabric. The results showed that the UV protection property of cotton fabrics after assembled TiO2 nanoparticles was still maintained at a high level after five launderings.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Xiao, X, Liu, X, Cao, G, “Atomic Layer Deposition TiO2/Al2O3 Nanolayer of Dyed Polyamide/Aramid Blend Fabric for High Intensity UV Light Protection.” Polym. Eng. Sci., 55 1296–1302 (2015)

    Article  Google Scholar 

  2. Gorenšek, M, Recelj, P, “Nanosilver Functionalized Cotton Fabric.” Text. Res. J., 77 138–141 (2007)

    Article  Google Scholar 

  3. Zhang, Y, Yu, L, Ke, S, “TiO2/SiO2 Hybrid Nanomaterials: Synthesis and Variable UV-Blocking Properties.” J. Sol-Gel. Sci. Technol., 58 326–329 (2011)

    Article  Google Scholar 

  4. Fakin, D, Veronovski, N, Ojstršek, A, “Synthesis of TiO2–SiO2 Colloid and its Performance in Reactive Dyeing of Cotton Fabrics.” Carbohydr. Polym., 88 992–1001 (2012)

    Article  Google Scholar 

  5. Ghoranneviss, M, Shahidi, S, “Effect of Various Metallic Salts on Antibacterial Activity and Physical Properties of Cotton Fabrics.” J. Ind. Text., 42 193–203 (2013)

    Article  Google Scholar 

  6. Sasipriya, K, Manivasakan, P, Yuvakkumar, R, “Enhancement of UV Property on Cotton Fabric by TiO2 Nanorods.” Synth. React. Inorg. Met. Org. Nano-Met. Chem., 44 748–758 (2014)

    Article  Google Scholar 

  7. Pakdel, E, Daoud, WA, Sun, L, “Visible and UV Functionality of TiO2 Ternary Nanocomposites on Cotton.” Appl. Surf. Sci., 321 447–456 (2014)

    Article  Google Scholar 

  8. Pakdel, E, Daoud, WA, Afrin, T, Sun, L, Wang, XG, “Enhanced Antimicrobial Coating on Cotton and its Impact on UV Protection and Physical Characteristics.” Cellulose, 24 4003–4015 (2017)

    Article  Google Scholar 

  9. Pakdel, E, Daoud, WA, Wang, XG, “Assimilating the Photo-Induced Functions of TiO2-Based Compounds in Textiles: Emphasis on the Sol–Gel Process.” Text. Res. J., 85 1404–1428 (2015)

    Article  Google Scholar 

  10. Wang, RH, Wang, XG, Xin, JH, “Advanced Visible-Light-Driven Self-cleaning Cotton by Au/TiO2/SiO2 Photocatalysts.” ACS Appl. Mater. Interfaces, 2 82–85 (2009)

    Article  Google Scholar 

  11. Doganli, G, Yuzer, B, Aydin, I, Gultekin, T, Con, AH, Selcuk, H, Palamutcu, S, “Functionalization of Cotton Fabric with Nanosized TiO2 Coating for Self-cleaning and Antibacterial Property Enhancement.” J. Coat. Technol. Res., 13 257–265 (2016)

    Article  Google Scholar 

  12. Gashti, MP, Pakdel, E, Alimohammadi, F, “Nanotechnology-Based Coating Techniques for Smart Textiles.” In: Hu, J (ed.) Active Coatings for Smart Textiles, pp. 243–268. Woodhead Publishing (2016)

  13. Hyde, GK, McCullen, SD, Jeon, S, “Atomic Layer Deposition and Biocompatibility of Titanium Nitride Nano-Coatings on Cellulose Fiber Substrates.” Biomed. Mater., 4 025001 (2009)

    Article  Google Scholar 

  14. Lu, H, Fei, B, Xin, JH, “Fabrication of UV-Blocking Nanohybrid Coating via Miniemulsion Polymerization.” J. Colloid Interface Sci., 300 111–116 (2006)

    Article  Google Scholar 

  15. Daoud, WA, Xin, JH, “Nucleation and Growth of Anatase Crystallites on Cotton Fabrics at Low Temperatures.” J. Am. Ceram. Soc., 87 953–955 (2004)

    Article  Google Scholar 

  16. Sadr, FA, Montazer, M, “In Situ Sonosynthesis of Nano TiO2 on Cotton Fabric.” Ultrason. Sonochem., 21 681–691 (2014)

    Article  Google Scholar 

  17. Ugur, ŞS, Sariişik, M, Aktaş, AH, “The Fabrication of Nanocomposite Thin Films with TiO2 Nanoparticles by the Layer-by-Layer Deposition Method for Multifunctional Cotton Fabrics.” Nanotechnology, 21 325603 (2010)

    Article  Google Scholar 

  18. Decher, G, “Fuzzy Nanoassemblies: Toward Layered Polymeric Multicomposites.” Science, 277 1232–1237 (1997)

    Article  Google Scholar 

  19. Decher, G, Eckle, M, Schmitt, J, Struth, B, “Layer-by-Layer Assembled Multicomposite Films.” Curr. Opin. Colloid. In., 3 32–39 (1998)

    Article  Google Scholar 

  20. Zhou, CH, Shen, ZF, Liu, LH, “Preparation and Functionality of Clay-Containing Films.” J. Mater. Chem., 21 15132–15153 (2011)

    Article  Google Scholar 

  21. Sun, J, Wu, T, Liu, F, “Covalently Attached Multilayer Assemblies by Sequential Adsorption of Polycationic Diazo-Resins and Polyanionic Poly (Acrylic Acid).” Langmuir, 16 4620–4624 (2000)

    Article  Google Scholar 

  22. Yan, D, Lu, J, Wei, M, “Heterogeneous Transparent Ultrathin Films with Tunable-Color Luminescence Based on the Assembly of Photoactive Organic Molecules and Layered Double Hydroxides.” Adv. Funct. Mater., 21 2497–2505 (2011)

    Article  Google Scholar 

  23. Wang, Q, Hauser, PJ, “Developing a Novel UV Protection Process for Cotton Based on Layer-by-Layer Self-assembly.” Carbohydr. Polym., 81 491–496 (2010)

    Article  Google Scholar 

  24. Zhao, Y, Xu, Z, Wang, X, “Superhydrophobic and UV-Blocking Cotton Fabrics Prepared by Layer-by-Layer Assembly of Organic UV Absorber Intercalated Layered Double Hydroxides.” Appl. Surf. Sci., 286 364–370 (2013)

    Article  Google Scholar 

  25. Uğur, ŞS, Sarıışık, M, Aktaş, AH, “Nano-Al2O3 Multilayer Film Deposition on Cotton Fabrics by Layer-by-Layer Deposition Method.” Mater. Res. Bull., 46 1202–1206 (2011)

    Article  Google Scholar 

  26. Liu, J, Wang, Q, Fan, XR, “Layer-by-Layer Self-assembly of TiO2 Sol on Wool to Improve its Anti-ultraviolet and Anti-ageing Properties.” J. Sol-Gel. Sci. Technol., 62 338–343 (2012)

    Article  Google Scholar 

  27. Iamphaojeen, Y, Siriphannon, P, “Immobilization of Zinc Oxide Nanoparticles on Cotton Fabrics Using Poly 4-Styrenesulfonic Acid Polyelectrolyte.” Int. J. Mater. Res., 103 643–647 (2012)

    Article  Google Scholar 

  28. Hyde, K, Hinestroza, JP, “Effect of Surface Cationization on the Conformal Deposition of Polyelectrolytes over Cotton Fibers.” Cellulose, 14 615–623 (2007)

    Article  Google Scholar 

  29. Fan, L, Cao, M, Gao, S, “Preparation and Characterization of a Quaternary Ammonium Derivative of Pectin.” Carbohydr. Polym., 88 707–712 (2012)

    Article  Google Scholar 

  30. Khalil-Abad, MS, Yazdanshenas, ME, Nateghi, MR, “Effect of Cationization on Adsorption of Silver Nanoparticles on Cotton Surfaces and its Antibacterial Activity.” Cellulose, 16 1147–1157 (2009)

    Article  Google Scholar 

  31. Chadwick, MD, Goodwin, JW, Lawson, EJ, “Surface Charge Properties of Colloidal Titanium Dioxide in Ethylene Glycol and Water.” Colloids Surf. A., 203 229–236 (2002)

    Article  Google Scholar 

  32. Gorjanc, M, Jazbec, K, Šala, M, “Creating Cellulose Fibres with Excellent UV Protective Properties Using Moist CF4 Plasma and ZnO Nanoparticles.” Cellulose, 21 3007–3021 (2014)

    Article  Google Scholar 

  33. Nateghi, MR, Shateri-Khalilabad, M, “Silver Nanowire-Functionalized Cotton Fabric.” Carbohydr. Polym., 117 160–168 (2015)

    Article  Google Scholar 

Download references

Acknowledgments

This research was supported by the National Natural Science Foundation of China (51503164). Also, this research was supported by the Scientific Research Project of Hubei Provincial Department of Education (Q20171611), the Wuhan Textiles University Research Fund (142078003, ZDSYS201712), and the Collaborative Innovation Plan of Hubei Province for Key Technology of Eco-Ramie Industry (E JIAO KE HAN 2014 No. 8).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Jianhua Ran or Jihong Wu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Cheng, D., He, M., Cai, G. et al. Durable UV-protective cotton fabric by deposition of multilayer TiO2 nanoparticles films on the surface. J Coat Technol Res 15, 603–610 (2018). https://doi.org/10.1007/s11998-017-0021-8

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11998-017-0021-8

Keywords

Navigation