Skip to main content
Log in

Corrosion protection of aluminum 6061 in NaCl solution by silane–zeolite composite coatings

  • Published:
Journal of Coatings Technology and Research Aims and scope Submit manuscript

Abstract

Anticorrosion properties of silane–zeolite composite coatings applied on aluminum substrates have been investigated. The composite coatings were prepared with different zeolite microparticles concentration (from 500 to 8000 ppm). Physico-chemical tests (Fourier transform infrared spectroscopy, adhesion, scanning electron microscopy, and contact angle measurements) have been carried out to evaluate the homogeneity and structural properties of the coatings. The coatings that resulted were highly hydrophobic for all zeolite contents and showed a relatively good adhesion performance. Corrosion protection performances in 3.5% NaCl solution were evaluated by means of polarization tests, evidencing good barrier characteristics of the composite layer.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Deflorian, F, Rossi, S, Fedrizzi, L, “Silane Pre-treatments on Copper and Aluminium.” Electrochim. Acta, 51 (27) 6097–6103 (2006)

    Article  CAS  Google Scholar 

  2. Frignani, A, Zucchi, F, Trabanelli, G, Grassi, V, “Protective Action Towards Aluminium Corrosion by Silanes with a Long Aliphatic Chain.” Corros. Sci., 48 2258–2273 (2006)

    Article  CAS  Google Scholar 

  3. Hu, JM, Liang, L, Zhang, JQ, Cao, CN, “Electrodeposition of Silane Films on Aluminum Alloys for Corrosion Protection.” Prog. Org. Coat., 58 (4) 265–271 (2007)

    Article  CAS  Google Scholar 

  4. Deflorian, F, Rossi, S, Fedrizzi, L, Fedel, M, “Integrated Electrochemical Approach for the Investigation of Silane Pre-treatments for Painting Copper.” Prog. Org. Coat., 63 (3) 338–344 (2008)

    Article  CAS  Google Scholar 

  5. Van Ooij, WJ, Zhu, D, Stacy, M, Seth, A, Mugada, T, Gandhi, J, Puomi, P, “Corrosion Protection Properties of Organofunctional Silanes—An Overview.” Tsinghua Sci. Technol., 10 (6) 639–669 (2005)

    Article  Google Scholar 

  6. Palanivel, V, Zhu, D, Van Ooij, WJ, “Nanoparticle-Filled Silane Films as Chromate Replacements for Aluminium Alloys.” Prog. Org. Coat., 47 384–392 (2003)

    Article  CAS  Google Scholar 

  7. Palanivel, V, Huang, Y, Van Ooij, WJ, “Effects of Addition of Corrosion Inhibitors to Silane Films on the Performance of AA2024-T3 in a 0.5 M NaCl Solution.” Prog. Org. Coat., 53 (2) 153–168 (2005)

    Article  CAS  Google Scholar 

  8. Montemor, MF, Pinto, R, Ferreira, MGS, “Chemical Composition and Corrosion Protection of Silane Films Modified with CeO2 Nanoparticles.” Electrochem. Acta, 54 (22) 5179–5189 (2009)

    Article  CAS  Google Scholar 

  9. Palomino, LM, Suegama, PH, Aoki, IV, Montemor, MF, De Melo, HG, “Electrochemical Study of Modified Non-Functional Bis-Silane Layers on Al Alloy 2024-T3.” Corros. Sci., 50 1258–1266 (2008)

    Article  CAS  Google Scholar 

  10. Deflorian, F, Rossi, S, Fedel, M, Motte, C, “Electrochemical Investigation of High-Performances Silane Sol–Gel Films Containing Clay Nanoparticles.” Prog. Org. Coat., 69 158–166 (2010)

    Article  CAS  Google Scholar 

  11. Varma, PC, Colreavy, J, Cassidy, J, Oubaha, M, McDonagh, C, Duffy, B, “Corrosion Protection of AA 2024-T3 Aluminium Alloy Using 3,4-Diaminobenzoic Acid Chelated Zirconium–Silane Hybrid Sol–Gels.” Thin Solid Films, 518 (20) 5753–5761 (2010)

    Article  CAS  Google Scholar 

  12. Snihirova, D, Lamaka, SV, Taryba, M, Salak, AN, Kallip, S, Zheludkevich, ML, Ferreira, MGS, Montemor, MF, “Hydroxyapatite Microparticles as Feedback-Active Reservoirs of Corrosion Inhibitors.” Appl. Mater. Interfaces, 2 (11) 3011–3022 (2010)

    Article  CAS  Google Scholar 

  13. Phanasgaonkar, A, Raja, VS, “Influence of Curing Temperature, Silica Nanoparticles- and Cerium on Surface Morphology and Corrosion Behaviour of Hybrid Silane Coatings on Mild Steel.” Surf. Coat. Technol., 203 2260–2271 (2009)

    Article  CAS  Google Scholar 

  14. Kawai, T, Tsusumi, K, “Reactivity of Silanol Groups on Zeolite Surfaces.” Colloid Polym. Sci., 276 (11) 992–998 (1998)

    Article  CAS  Google Scholar 

  15. Cejka, J, Van Bekkum, H, Corma, A, Schueth, F, Introduction to Zeolite Science and Practice. Elsevier Science, Amsterdam (2001)

    Google Scholar 

  16. Cai, R, Yan, Y, “Corrosion-Resistant Zeolite Coatings.” Corrosion, 64 (3) 271–278 (2008)

    Article  CAS  Google Scholar 

  17. Bevign, DE, McDonnell, AMP, Yang, W, Yan, Y, “Corrosion Resistant High-Silica–Zeolite MFI Coating.” J. Electrochem. Soc., 153 (8) B325–B329 (2006)

    Article  Google Scholar 

  18. Zandizand, R, Ershadlangroudi, A, Rahimi, A, “Silica Cased Organic–Inorganic Hybrid Nanocomposite Coatings for Corrosion Protection.” Prog. Org. Coat., 53 286–291 (2005)

    Article  CAS  Google Scholar 

  19. Bonaccorsi, L, Proverbio, E, Freni, A, Restuccia, G, “In Situ Growth of Zeolites on Metal Foamed Supports for Adsorption Heat Pumps.” J. Chem. Eng. Jpn., 40 (13) 1307–1312 (2007)

    Article  Google Scholar 

  20. Plueddemann, EP, Silane Coupling Agents, 2nd ed. Plenum Press, New York (1991)

    Google Scholar 

  21. Correa-Borroel, AL, Gutierrez, S, Arce, E, Cabrera-Sierra, R, Herrasti, P, “Organosilanes and Polypyrrole as Anticorrosive Treatment of Aluminium 2024.” J. Appl. Electrochem., 39 (12) 2385–2395 (2009)

    Article  CAS  Google Scholar 

  22. Franquet, A, Terryn, H, Bertrand, P, Vereecken, J, “Use of Optical Methods to Characterize Thin Silane Films Coated on Aluminium.” Surf. Interface Anal., 34 25–29 (2002)

    Article  CAS  Google Scholar 

  23. Han, YH, Taylor, A, Mantle, MD, Knowle, KM, “Sol–Gel-Derived Organic–Inorganic Hybrid Materials.” J. Non-Cryst. Solids, 353 313–320 (2007)

    Article  CAS  Google Scholar 

  24. Van Ooij, WJ, Zhu, D, “Electrochemical Impedance Spectroscopy of Bis-[Triethoxysilylpropyl]tetrasulfide on Al-2024-T3 Substrates.” Corrosion, 57 413–427 (2001)

    Article  Google Scholar 

  25. Tiwari, A, Hihara, LH, “High Silicone Content Barrier Coatings for Corrosion Protection of Metals”. Tri-Service Corrosion Conference 2007

  26. Almeida, RM, Pantano, CG, “Structural Investigation of Silica Gel Films by Infrared Spectroscopy.” J. Appl. Phys., 68 (8) 4225–4232 (1990)

    Article  CAS  Google Scholar 

  27. Mittal, KL, Contact Angle Wettability an Adhesion, 3rd ed. VSPBV, Boston (2003)

    Google Scholar 

  28. Hiemenz, PC, Rajagopalan, R, Principles of Colloid and Surface Chemistry. Marcel Dekker, New York (1997)

    Google Scholar 

  29. Li, Y, Guana, HN, Chunga, TS, Kulprathipanja, S, “Effects of Novel Silane Modification of Zeolite Surface on Polymer Chain Rigidification and Partial Pore Blockage in Polyethersulfone (PES)–Zeolite A Mixed Matrix Membranes.” J. Memb. Sci., 275 17–28 (2006)

    Article  CAS  Google Scholar 

  30. Matsumoto, A, Tsutsumi, K, Schumacher, K, Unger, KK, “Surface Functionalization and Stabilization of Mesoporous Silica Spheres by Silanization and Their Adsorption Characteristics.” Langmuir, 18 (10) 4014–4019 (2002)

    Article  CAS  Google Scholar 

  31. Larsen, SC, “Nanocrystalline Zeolites and Zeolite Structures: Synthesis, Characterisation and Applications.” J. Phys. Chem. C, 111 18464–18474 (2007)

    Article  CAS  Google Scholar 

  32. Lee, JY, Lee, SH, Kim, SW, “Surface Tension of Silane Treated Natural Zeolite.” Mater. Chem. Phys., 63 251–255 (2000)

    Article  CAS  Google Scholar 

  33. Wasserman, SR, Tao, YT, Whitesides, GM, “Structure and Reactivity of Alkylsiloxane Monolayers Formed by Reaction of Alkyltrichlorosilanes on Silicon Substrates.” Langmuir, 5 (4) 1074–1087 (1989)

    Article  CAS  Google Scholar 

  34. Almanza-Workman, AM, Raghavan, S, Deymier, P, Monk, DJ, Roop, R, “Water Dispersible Silanes for Wettability Modification of Polysilicon.” J. Electrochem. Soc., 149 (1) H6–H11 (2002)

    Article  CAS  Google Scholar 

  35. Duchet, J, Gerard, JF, Chapel, JP, Chabert, B, “Preparation of Well-Structured Organosilane Layers on Silica.” Compos. Interfaces, 8 (3–4) 177–187 (2001)

    Article  CAS  Google Scholar 

  36. Van Schaftinghen, T, Le Pen, C, Terryn, H, Horzenberger, F, “Investigation of the Barrier Properties of Silanes on Cold Rolled Steel.” Electrochim. Acta, 49 (17–18) 2997–3004 (2004)

    Article  Google Scholar 

  37. Zhu, D, Van Ooij, WJ, “Corrosion Protection of Metals by Water-Based Silane Mixtures of Bis-[Trimethoxysilylpropyl]Amine and Vinyltriacetoxysilane.” Prog. Org. Coat., 49 (1) 42–53 (2004)

    Article  CAS  Google Scholar 

  38. Wicks, ZW, Jones, FN, Pappas, SP, Wicks, DA, Organic Coating: Science and Technology. Wiley, Hoboken, NJ (2006)

    Google Scholar 

  39. Suegama, PH, De Melo, HG, Recco, A, Tschiptschin, AP, Aoki, IV, “Corrosion Behavior of Carbon Steel Protected with Single and Bi-Layer of Silane Films Filled with Silica Nanoparticles.” Surf. Coat. Technol., 202 (13) 2850–2858 (2008)

    Article  CAS  Google Scholar 

  40. Liu, T, Chen, S, Cheng, S, Tian, J, Chang, X, Yin, Y, “Corrosion Behaviour of Super-Hydrophobic Surface on Copper in Seawater.” Electrochim. Acta, 52 8003–8007 (2007)

    Article  CAS  Google Scholar 

  41. Lunarska, E, Chernyayeva, O, “Effect of Corrosion Inhibitors on Hydrogen Uptake by Al from NaOH Solution.” Int. J. Hydrog. Energy, 31 285–293 (2006)

    Article  CAS  Google Scholar 

  42. Woo, RSC, Zhu, H, Chow, MMk, Leung, CKY, Kim, JK, “Barrier Performance of Silane–Clay Nanocomposite Coatings on Concrete Structure.” Compos. Sci. Technol., 68 (14) 2828–2836 (2008)

    Article  CAS  Google Scholar 

  43. Montemor, MF, Cabral, AM, Zheludkevich, ML, Ferreira, MGS, “The Corrosion Resistance of Hot Dip Galvanized Steel Pretreated with Bis-Functional Silanes Modified with Microsilica.” Surf. Coat. Technol., 200 (9) 2875–2885 (2006)

    Article  CAS  Google Scholar 

  44. Schueremans, L, Gemert, DV, Giessler, S, “Chloride Penetration in RC-Structures in Marine Climate: In Site Survey, Analysis Model and Benefit of a Preventive Hydrophobic Treatment”. Proceeding of the International Workshop on Durability of Reinforced Concrete under Combined Mechanical and Climatic Loads (CMCL), Qingdao, China, October 2005.

  45. Bonaccorsi, L, Calabrese, L, Proverbio, E, “Low Temperature One-Step Synthesis of Zeolite Y Coating on Aluminium Substrates.” Microporous Mesoporous Mater., 144 (1–3) 40–45 (2011)

    Article  CAS  Google Scholar 

  46. Rolison, DR, “Zeolite-Modified Electrodes and Electrode-Modified Zeolites.” Chem. Rev., 90 867–878 (1990)

    Article  CAS  Google Scholar 

  47. Walcarius, A, “Zeolite-Modified Electrodes: Analytical Applications and Prospects.” Electroanalysis, 8 971–986 (1996)

    Article  CAS  Google Scholar 

  48. Rolison, DR, Bessel, CA, “Electrocatalysis and Charge-Transfer Reactions at Redox-Modified Zeolites.” Acc. Chem. Res., 33 737–744 (2000)

    Article  CAS  Google Scholar 

  49. Walcarius, A, “Electroanalytical Applications of Microporous Zeolites and Mesoporous (Organo)Silicas: Recent Trends.” Electroanalysis, 20 (7) 711–738 (2008)

    Article  CAS  Google Scholar 

  50. Bodoardo, S, Geobaldo, F, Penazzi, N, Arrabito, M, Rivetti, F, Spanà, G, Lamberti, C, Zecchina, A, “Cyclic Voltammetric Characterisation of Titanium in Titano-Silicates Molecular Sieves.” Electrochem. Commun., 2 349–352 (2000)

    Article  CAS  Google Scholar 

  51. Zhu, D, “Corrosion Protection of Metals by Silane Surface Treatment”, Ph.D Thesis, University of Cincinnati, Engineering (2005)

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Luigi Calabrese.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Calabrese, L., Bonaccorsi, L. & Proverbio, E. Corrosion protection of aluminum 6061 in NaCl solution by silane–zeolite composite coatings. J Coat Technol Res 9, 597–607 (2012). https://doi.org/10.1007/s11998-011-9391-5

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11998-011-9391-5

Keywords

Navigation