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Synergistic effect of blended primary and secondary amines functionalized onto the silica on CO2 capture performance

  • Catalysis, Reaction Engineering
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Amine-functionalized silica sorbents were synthesized by blending (3-aminopropyl)trimethoxysilane (1NSP) and [3-(methylamino)propyl]trimethoxysilane (1NS-S) of varying proportions and incorporating it in the support via incipient wetness technique. Adsorption characteristics were examined at a design adsorption temperature of 30 oC. The blended amine adsorbents exhibited higher CO2 adsorption capacity (5.6-6.4 wt%) and CO2/N efficiency (0.47-0.48) than 1NS-P and 1NS-S. Among the blended amine adsorbents synthesized in this work, 1NS-PS-50, which has 50% primary amine and 50% secondary amine, is the most ideal for post-combustion CO2 capture application because it has high CO2 adsorption capacity, high CO2/N efficiency, and better performance than its diamine counterpart, N-[3-(trimethoxysilyl)propyl]ethylenediamine.

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References

  1. B. P. Spigarelli and S.K. Kawatra, J. CO 2 . Util., 1, 69 (2013).

    Article  CAS  Google Scholar 

  2. D. Aaron and C. Tsouris, Sep. Sci. Technol., 40, 321 (2005).

    Article  CAS  Google Scholar 

  3. A. Olajire, Energy, 35, 2610 (2010).

    Article  CAS  Google Scholar 

  4. R. Huaman and S. Lourenco, J. Fundam. Renew. Energy Appl., 5, 1 (2015).

    Google Scholar 

  5. I. Sreedhar, T. Nahar, A. Venugopal and B. Srinivas, Renew. Sustain. Energy Rev., 76, 1080 (2017).

    Article  CAS  Google Scholar 

  6. E. Sanz-Pérez, M. Olivares-Marin, A. Arencibia, R. Sanz, G. Calleja and M. Maroto-Valer, Int. J. Greenh. Gas Control, 17, 366 (2013).

    Article  CAS  Google Scholar 

  7. D.P. Bezerra, R. S. Oliveira, R. S. Vieira, C. L. Cavalcante and D. C. S. Azevedo, Adsorption, 17, 235 (2011).

    Article  CAS  Google Scholar 

  8. C. Chen, S. Zhang, K.H. Row and W. S. Ahn, J. Energy Chem., 26, 868 (2017).

    Article  CAS  Google Scholar 

  9. B. Zhao, F. Liu, Z. Cui, C. Liu, H. Yue, S. Tang, Y. Liu, H. Lu and B. Liang, Appl. Energy, 185, 362 (2017).

    Article  CAS  Google Scholar 

  10. S. Ahmed, A. Ramli and S. Yusup, Int. J. Greenh. Gas Control, 51, 230 (2016).

    Article  CAS  Google Scholar 

  11. P. Brúder and H. F. Svendsen, Energy Procedia, 23, 45 (2012).

    Article  CAS  Google Scholar 

  12. C.H. Chen, D. Shimon, J. J. Lee, S.A. Didas, A.K. Mehta, C. Sievers, C.W. Jones and S. E. Hayes, Environ. Sci. Technol., 51, 6553 (2017).

    Article  CAS  PubMed  Google Scholar 

  13. S. Gangarapu, A.T.M. Marcelis and H. Zuilhof, ChemPhysChem., 14, 3936 (2013).

    Article  CAS  PubMed  Google Scholar 

  14. D. Madden and T. Curtin, Micropor. Mesopor. Mater., 228, 310 (2016).

    Article  CAS  Google Scholar 

  15. W. Srisang, F. Pouryousefi, P. A. Osei, B. Decardi-Nelson, A. Akachuku, P. Tontiwachwuthikul and R. Idem, Int. J. Greenh. Gas Control, 69, 52 (2018).

    Article  CAS  Google Scholar 

  16. Q. Yang, M. Bown, A. Ali, D. Winkler, G. Puxty and M. Attalla, Energy Procedia, 1, 955 (2009).

    Article  CAS  Google Scholar 

  17. C. Nwaoha, T. Supap, R. Idem, C. Saiwan, P. Tontiwachwuthikul, M. AL-Marri and A. Benamor, Petroleum, 3, 10 (2017).

    Article  Google Scholar 

  18. C. Perinu, I. M. Bernhardsen, H. F. Svendsen and K. J. Jens, Energy Procedia, 114, 1949 (2017).

    Article  CAS  Google Scholar 

  19. J.M. Celedonio, J. H. Park and Y. S. Ko, Res. Chem. Intermed., 42, 141 (2015).

    Article  CAS  Google Scholar 

  20. J.M. Celedonio, R. M. Pacia and Y. S. Ko, Catal. Today, 303, 55 (2017).

    Article  CAS  Google Scholar 

  21. J.H. Park, J.M. Celedonio, H.W. Seo, Y.K. Park and Y. S. Ko, Catal. Today, 265, 68 (2016).

    Article  CAS  Google Scholar 

  22. E. S. Sanz-Pérez, C.R. Murdock, S. A. Didas and C.W. Jones, Chem. Rev., 116, 11840 (2017).

    Article  CAS  Google Scholar 

  23. D. Shimon, C. H. Chen, J. J. Lee, S. A. Didas, C. Sievers, C.W. Jones and S. E. Hayes, Environ. Sci. Technol., 52, 1488 (2018).

    Article  CAS  PubMed  Google Scholar 

  24. D.H. Ripin and D. A. Evans, PKa’s of CH Bonds at Heteroatom Substituted Carbon & References (2014).

    Google Scholar 

  25. D. Fernandes, W. Conway, R. Burns, G. Lawrance, M. Maeder and G. Puxty, J. Chem. Thermodyn., 54, 183 (2012).

    Article  CAS  Google Scholar 

  26. A. Heydari-Gorji and A. Sayari, Ind. Eng. Chem. Res., 51, 6887 (2012).

    Article  CAS  Google Scholar 

  27. C. S. Srikanth and S.S.C. Chuang, J. Phys. Chem. C., 117, 9196 (2013).

    Article  CAS  Google Scholar 

  28. W. S. Choi, K. M. Min, C. H. Kim, Y. S. Ko, J.W. Jeon, H.W. Seo, Y. K. Park and M. K. Choi, Nat. Commun., 7, 12640 (2016).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

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Acknowledgements

This work was supported by a National Research Foundation of Korea (NRF) grant funded by the Korean government (MSIP) (2016R1D1A1B01009941). This work was also supported by the Human Resources Program in Energy Technology of the Korea Institute of Energy Technology Evaluation and Planning (KETEP), granted financial resource from the Ministry of Trade, Industry & Energy, Republic of Korea (No. 20194010201730).

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Authors and Affiliations

  1. Department of Chemical Engineering, Kongju National University, 1223-24 Cheonan-daero, Seobuk-gu, Cheonan-si, Chungcheongnam-do, 31080, Korea

    Clinton Manianglung, Rose Mardie Pacia & Young Soo Ko

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  1. Clinton Manianglung
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  2. Rose Mardie Pacia
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  3. Young Soo Ko
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Correspondence to Young Soo Ko.

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Manianglung, C., Pacia, R.M. & Ko, Y.S. Synergistic effect of blended primary and secondary amines functionalized onto the silica on CO2 capture performance. Korean J. Chem. Eng. 36, 1267–1273 (2019). https://doi.org/10.1007/s11814-019-0321-z

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  • DOI: https://doi.org/10.1007/s11814-019-0321-z

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