Abstract
Q&P steels possessing a combination of ultra-high product of strength and tensile elongation (PSE) and superior impact toughness was obtained by tailoring the micromechanical deformation ability of retained austenite (RA) and martensite via low-temperature partitioning. Our results indicate that impact toughness is more susceptible to the heterogeneity of mechanical properties of constituent phases than its tensile mechanical properties. Through optimizing the difference between the constituent phases, the impact toughness can be improved significantly by the enhancement of micromechanical deformation ability of tempered martensite (TM) and corresponding alleviation of deformation incompatibility. Simultaneously, high PSE was preserved by using the deformation potential of RA and its transformation-induced plasticity effect. Load–unload–reload (LUR) tests were carried out to characterize the evolution of flow stress components and the influence of partitioning temperatures on the degree of deformation inhomogeneity between constituent phases during plastic deformation. Furthermore, the mechanical properties and micromechanical deformation ability of the constituent phases were quantitatively characterized using the nanoindentation technique, which indicates that degree of incompatible deformation is alleviated for steels partitioned at relatively high temperatures due to the enhancement of the deformation ability of TM. The underlying relationship between the dynamic transformation of metastable austenite based on the Olson and Cohen model, and high PSE was elucidated. As the partitioning temperature increases, the mechanical stability of RA increases, which is attributed to the synergistic effect of carbon partitioning and the improvement of compatible deformation capability of TM and RA, resulting in an excellent combination of concurrent ductility and impact toughness. Based on the above characterization and analysis, further investigation into the fractured morphology of impact and edge notched specimens was carried out to provide a comprehensive understanding of the damage and fracture mechanism, and to reveal the reasons for the improvement of mechanical properties. The nucleation position and propagation path of microvoids and microcracks depend on the deformation compatibility of constituent phases and the morphology of cementite in tempered martensite. The nucleation sites of microcracks and microvoids at the phase interface, due to stress concentration and dislocation pile-ups for incompatibility deformation of constituent phases, are substituted with nucleation sites at fractured cementite in TM with the increasing partitioning temperature.
Similar content being viewed by others
References
O. Grässel, L. Krüger, G. Frommeyer and L. Meyer, International Journal of plasticity 2000, vol. 16, pp. 1391-1409.
D. De Knijf, R. Petrov, C. Föjer and L. A. Kestens, Materials Science and Engineering: A 2014, vol. 615, pp. 107-115.
X. Wang, Z. Guo and Y. Rong, Materials Science and Engineering: A 2011, vol. 529, pp. 35-40.
Z. Li, K. G. Pradeep, Y. Deng, D. Raabe and C. C. Tasan, Nature 2016, vol. 534, pp. 227–230.
B. He, B. Hu, H. Yen, G. Cheng, Z. Wang, H. Luo and M. Huang, Science 2017, vol. 357, pp. 1029-1032.
T. Tsuchiyama, J. Tobata, T. Tao, N. Nakada and S. Takaki, Materials Science and Engineering: A 2012, vol. 532, pp. 585-592.
E. Pereloma, K. Russell, M. Miller and I. B. Timokhina, Scripta materialia 2008, vol. 58, pp. 1078-1081.
L. Baker, S. Daniel and J. Parker, Materials science and technology 2002, vol. 18, pp. 355-368.
J. Speer, D. K. Matlock, B. C. De Cooman and J. G. Schroth, Acta Materialia 2003, vol. 51, pp. 2611-2622.
D. K. Matlock, V. Brautigam and J. G. Speer, In Materials Science Forum, (Trans Tech Publications Ltd., Zurich-Uetikon, Switzerland: 2003), pp 1089–94.
D. K. Matlock and J. G. Speer, In Microstructure and texture in steels, (Springer, New York, 2009), pp 185–205.
J. G. Speer, F. C. R. Assunção, D. K. Matlock and D. V. Edmonds, Materials Research 2005, vol. 8, pp. 417-423.
J. G. Speer, D. V. Edmonds, F. C. Rizzo and D. K. Matlock, Current Opinion in Solid State and Materials Science 2004, vol. 8, pp. 219-237.
T. Hsu and Z. Y. Xu, In Materials Science Forum, (Trans Tech Publ, Zürich, 2007), pp 2283–86.
H. Li, X. Lu, W. Li and X. Jin, Metallurgical and Materials Transactions A 2010, vol. 41, pp. 1284-1300.
J. Mola and B. C. De Cooman, Metallurgical and Materials Transactions A 2013, vol. 44, pp. 946-967.
E. De Moor, S. Lacroix, A. Clarke, J. Penning and J. Speer, Metallurgical and Materials Transactions A 2008, vol. 39, pp. 2586–2595.
E. J. Seo, L. Cho and B. C. De Cooman, Metallurgical and Materials Transactions A 2016, vol. 47, pp. 3797-3802.
H. Zhao, W. Li, L. Wang, S. Zhou and X. Jin, Metallurgical and Materials Transactions A 2016, vol. 47, pp. 3943-3955.
S. Qin, Y. Liu, Q. Hao, Y. Wang, N. Chen, X. Zuo and Y. Rong, Metallurgical and Materials Transactions A 2015, vol. 46, pp. 4047-4055.
H. Yi, P. Chen, Z. Hou, N. Hong, H. Cai, Y. Xu, D. Wu and G. Wang, Scripta Materialia 2013, vol. 68, pp. 370-374.
Y.-j. Li, X.-l. Li, G. Yuan, J. Kang, D. Chen and G.-d. Wang, Materials Characterization 2016, vol. 121, pp. 157-165.
H. Liu, X. Lu, X. Jin, H. Dong and J. Shi, Scripta Materialia 2011, vol. 64, pp. 749-752.
X. Wu, P. Jiang, L. Chen, F. Yuan and Y. T. Zhu, Proceedings of the National Academy of Sciences 2014, vol. 111, pp. 7197-7201.
X. Wu, P. Jiang, L. Chen, J. Zhang, F. Yuan and Y. Zhu, Materials Research Letters 2014, vol. 2, pp. 185-191.
M. Yang, Y. Pan, F. Yuan, Y. Zhu and X. Wu, Materials Research Letters 2016, vol. 4, pp. 145-151.
M. Yang, F. Yuan, Q. Xie, Y. Wang, E. Ma and X. Wu, Acta Mater 2016, vol. 109, pp. 213-222.
H. Lee, M. C. Jo, S. S. Sohn, A. Zargaran, J. H. Ryu, N. J. Kim and S. Lee, Acta Mater 2018, vol. 147, pp. 247-260.
M. Calcagnotto, Y. Adachi, D. Ponge and D. Raabe, Acta Materialia 2011, vol. 59, pp. 658-670.
C. C. Tasan, M. Diehl, D. Yan, C. Zambaldi, P. Shanthraj, F. Roters and D. Raabe, Acta Materialia 2014, vol. 81, pp. 386-400.
C. C. Tasan, J. P. Hoefnagels, M. Diehl, D. Yan, F. Roters and D. Raabe, International Journal of Plasticity 2014, vol. 63, pp. 198-210.
J. Kadkhodapour, S. Schmauder, D. Raabe, S. Ziaei-Rad, U. Weber and M. Calcagnotto, Acta Mater 2011, vol. 59, pp. 4387-4394.
B. Fu, W. Yang, Y. Wang, L. Li, Z. Sun and Y. Ren, Acta Materialia 2014, vol. 76, pp. 342-354.
E. P. Bagliani, M. Santofimia, L. Zhao, J. Sietsma and E. Anelli, Materials Science and Engineering: A 2013, vol. 559, pp. 486-495.
X. Huang, W. Liu, Y. Huang, H. Chen and W. Huang, Journal of materials processing technology 2015, vol. 222, pp. 181-187.
L. Zhao, L. Qian, J. Meng, Q. Zhou and F. Zhang, Scripta Materialia 2016, vol. 112, pp. 96-100.
X. Wang, K. Wu, F. Hu, L. Yu and X. Wan, Scripta Materialia 2014, vol. 74, pp. 56-59.
G. Gao, B. An, H. Zhang, H. Guo, X. Gui and B. Bai, Materials Science and Engineering: A 2017, vol. 702, pp. 104-112.
G. Lai, W. Wood, R. Clark, V. Zackay and E. Parker, Metallurgical Transactions 1974, vol. 5, pp. 1663-1670.
C. Wang, M. Wang, J. Shi, W. Hui and H. Dong, Scripta Materialia 2008, vol. 58, pp. 492-495.
Y. Kimura, T. Inoue, F. Yin and K. Tsuzaki, Science 2008, vol. 320, pp. 1057-1060.
M. Koyama, Z. Zhang, M. Wang, D. Ponge, D. Raabe, K. Tsuzaki, H. Noguchi and C. C. Tasan, Science 2017, vol. 355, pp. 1055-1057.
G. Gao, H. Zhang, X. Gui, P. Luo, Z. Tan and B. Bai, Acta Mater 2014, vol. 76, pp. 425-433.
G. Gao, H. Zhang, Z. Tan, W. Liu and B. Bai, Materials Science and Engineering: A 2013, vol. 559, pp. 165-169.
G. Gao, H. Zhang, X. Gui, Z. Tan and B. Bai, Journal of Materials Science & Technology 2015, vol. 31, pp. 199-204.
L. Morsdorf, O. Jeannin, D. Barbier, M. Mitsuhara, D. Raabe and C. C. Tasan, Acta Mater 2016, vol. 121, pp. 202-214.
J. Zhao, A. De and B. De Cooman, Materials Letters 2000, vol. 44, pp. 374-378.
J. Snoek, Physica 1941, vol. 8, pp. 711-733.
W. Song, D. Bogdanovski, A. Yildiz, J. Houston, R. Dronskowski and W. Bleck, Metals 2018, vol. 8, pp. 44–60.
A. H. Cottrell and B. Bilby, Proceedings of the Physical Society. Section A 1949, vol. 62, pp. 49–62.
J.-B. Seol, J. Jung, Y. Jang and C. Park, Acta Mater 2013, vol. 61, pp. 558-578.
Steels: microstructure and properties. (1981).
D. V. Wilson and B. Russell, Acta Metallurgica 1960, vol. 8, pp. 468-479.
M. Calcagnotto, D. Ponge, E. Demir and D. Raabe, Materials Science and Engineering: A 2010, vol. 527, pp. 2738-2746.
A. Ramazani, K. Mukherjee, A. Schwedt, P. Goravanchi, U. Prahl and W. Bleck, International Journal of Plasticity 2013, vol. 43, pp. 128-152.
Y. Wei, Y. Li, L. Zhu, Y. Liu, X. Lei, G. Wang, Y. Wu, Z. Mi, J. Liu and H. Wang, Nature communications 2014, vol. 5, pp. 3580–3587.
Y. Li, W. Li, N. Min, W. Liu and X. Jin, Acta Mater 2017, vol. 139, pp. 96-108.
Y. Li, Y. Lu, W. Li, M. Khedr, H. Liu and X. Jin, Acta Mater 2018, vol. 158, pp. 79-94.
X. Feaugas, Acta Materialia 1999, vol. 47, pp. 3617-3632.
C. Sinclair, G. Saada and J. Embury, Philosophical Magazine 2006, vol. 86, pp. 4081-4098.
Y. Xiang and J. Vlassak, Acta Materialia 2006, vol. 54, pp. 5449-5460.
P. O. Guglielmi, M. Ziehmer and E. T. Lilleodden, Acta Mater 2018, vol. 150, pp. 195-205.
P. J. Konijnenberg, S. Zaefferer and D. Raabe, Acta Mater 2015, vol. 99, pp. 402-414.
C. Moussa, M. Bernacki, R. Besnard and N. Bozzolo, Ultramicroscopy 2017, vol. 179, pp. 63-72.
D. Wang, X. Lu, Y. Deng, X. Guo and A. Barnoush, Acta Mater 2019, vol. 166, pp. 618-629.
W. C. Oliver and G. M. Pharr, Journal of materials research 2004, vol. 19, pp. 3-20.
B. He, Z. Liang and M. Huang, Scripta Materialia 2018, vol. 150, pp. 134-138.
Y. Hong, C. Zhou, Y. Zheng, L. Zhang, J. Zheng, B. An, X. Chen and X. Wang, Materials Characterization 2017, vol. 127, pp. 35-40.
G. Cheng, K. S. Choi, X. Hu and X. Sun, Materials Science and Engineering: A 2016, vol. 652, pp. 384-395.
P. Tao, J.-m. Gong, Y.-f. Wang, Y. Jiang, Y. Li and W.-w. Cen, Results in Physics 2018, vol. 11, pp. 377-384.
A. K. Sachdev, Metallurgical Transactions A 1982, vol. 13, pp. 1793-1797.
P. Rodriguez, Bulletin of Materials Science 1984, vol. 6, pp. 653-663.
J. K. Kim, L. Chen, H. S. Kim, S. K. Kim, Y. Estrin and B. C. D. Cooman, Metallurgical & Materials Transactions A 2009, vol. 40, pp. 3147-3158.
R. W. Hayes, Acta Metallurgica 1983, vol. 31, pp. 365-371.
C. Gupta, J. K. Chakravartty, S. L. Wadekar and J. S. Dubey, Materials Science & Engineering A 2000, vol. 292, pp. 49-55.
G. Fribourg, Y. Bréchet, A. Deschamps and A. Simar, Acta Mater 2011, vol. 59, pp. 3621-3635.
Deschamps A, Decreus B, Geuser F, Dorin T and Weyland M, Acta Mater. 2013, 61, 4010-4021.
W. Xiaolei, Y. Muxin, Y. Fuping, W. Guilin, W. Yujie, H. Xiaoxu and Z. Yuntian, Proceedings of the National Academy of Sciences of the United States of America 2015, vol. 112, pp. 14501–14505.
W. Yinmin, C. Mingwei, Z. Fenghua and M. En, Nature 2002, vol. 419, pp. 912-915.
Z. Li and D. Wu, Isij Int 2006, vol. 46, pp. 121-128.
J. H. Choi, M. C. Jo, H. Lee, A. Zargaran, T. Song, S. S. Sohn, N. J. Kim and S. Lee, Acta Mater 2019, vol. 166, pp. 246-260.
H. Beattie and F. VerSnyder, Nature 1956, vol. 178, pp. 208-209.
F. R. N. Nabarro and T. Mura, Journal of Applied Mechanics 1981, vol. 48, pp. 451-452.
A. S. Argon, Journal of Applied Mechanics 1977, vol. 44, p. 801.
L. Thilly, S. V. Petegem, P. O. Renault, F. Lecouturier, V. Vidal, B. Schmitt and H. V. Swygenhoven, Acta Materialia 2009, vol. 57, pp. 3157-3169.
G. Saada, Philosophical Magazine 2006, vol. 86, pp. 4081-4098.
X. Yang, X. Ma, J. Moering, Z. Hao, W. Wei, Y. Gong, J. Tao, Y. Zhu and X. Zhu, Mater. Sci. Eng. A 2015, 645, 138.
H. Mughrabi, Acta Metallurgica 1983, vol. 31, pp. 1367-1379.
G. D. Moan and J. D. Embury, Acta Metallurgica 1979, vol. 27, pp. 903-914.
M. F. Ashby, Philosophical Magazine 1970, vol. 21, pp. 399-424.
H. Gao, Y. Huang, W. Nix and J. Hutchinson, Journal of the Mechanics and Physics of Solids 1999, vol. 47, pp. 1239-1263.
H. Gao and Y. Huang, Scripta Materialia 2003, vol. 48, pp. 113-118.
G. Olson and M. Cohen, Metallurgical transactions A 1975, vol. 6, pp. 791–795.
B. Fu, W. Yang, L. Li and Z. Sun, Materials Science and Engineering: A 2014, vol. 603, pp. 134-140.
L. Samek, E. De Moor, J. Penning and B. De Cooman, Metallurgical and Materials Transactions A 2006, vol. 37, pp. 109-124.
X. Tan, D. Ponge, W. Lu, Y. Xu, X. Yang, X. Rao, D. Wu and D. Raabe, Acta Mater 2019, vol. 165, pp. 561-576.
H. Luo, J. Shi, C. Wang, W. Cao, X. Sun and H. Dong, Acta Mater 2011, vol. 59, pp. 4002-4014.
D. Curry, Metal science 1980, vol. 14, pp. 319-326.
P. Pratt, Metal Science 1980, vol. 14, pp. 363-374.
W. Dahl and D. Dormagen, In Elastic-Plastic Fracture Mechanics, (Springer, New York 1985), pp 203-25.
Acknowledgments
The authors are thankful to the financial support of the National Key Research and Development Program of China (Grant No. 2017YFB0304401), National Natural Science Foundation of China (Grant Nos. 51901128, 51831002, 51201105 and 51601113), and the Startup Fund for Youngman Research at SJTU (SFYR at SJTU). Qiaoshi Zeng acknowledges the financial support from NSFC (Grant No. 51871054). The authors also gratefully acknowledge the support provided by the Shanghai Key Laboratory of Materials Laser Processing and Modification, Shanghai Jiao Tong University.
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Manuscript submitted September 25, 2019.
Electronic Supplementary Material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Du, H., Gong, Y., Liang, T. et al. Enhancement of Impact Toughness Via Tailoring Deformation Compatibility of Constituent Phases in Duplex Q&P Steel with Excellent Strength and Ductility. Metall Mater Trans A 51, 2097–2117 (2020). https://doi.org/10.1007/s11661-020-05701-8
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11661-020-05701-8