Abstract
The aim of this work was to evaluate how the physical properties of oleogels formulated with candelilla wax (CLX), monoglycerides (MG), and hardfat (HF) change with the addition of 1–30% water (w/w). Physical properties such as crystal microstructure, melting and rheological behavior, hardness, oil binding capacity, and thermal stability were evaluated. The oleogels evaluated in this study formed stable water-in-oil emulsion gels at 25 °C without the use of additional emulsifiers. The water addition in a range from 1 to 20% (w/w) resulted in a reduction in crystal size (Dm) from approximately 10 μm for the oleogel to less than 8 μm for the emulsion gels. This reduction in crystal size suggests that a well-organized crystalline network was formed in the emulsion gels resulting in improved physical properties. Emulsion gels with 1 to 20% (w/w) water showed a narrower melting profile, higher firmness, and lower oil loss compared to those of oleogel, and showed higher stability after temperature cycling at 40 °C. Samples with 1 and 5% w/w of water showed the best improvement in physical properties since they were 3 times harder than the respective oleogel with values of 0.42 N for the emulsions and 0.15 N for the oleogel. Also, the water addition increased G’ value from 4132.92 Pa for oleogel to 13157.78 Pa for emulsion with 1% water and 9702.35 Pa for emulsion with 5% water. The obtained results suggest that water amount up to 20% (w/w) can be added to oleogel to form stable emulsion gels.
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H.D. Batte, A.J. Wright, J.W. Rush, S.H.J. Idziak, A.G. Marangoni, Food Biophys. 2(1), 29–37 (2007)
E.D. Co, A.G. Marangoni, JAOCS, J. Am. Oil Chem. Soc. 89, 749 (2012)
L.S.K. Dassanayake, D.R. Kodali, S. Ueno, Curr. Opin. Colloid Interface Sci. 16(5), 432–439 (2011)
A.I. Blake, A.G. Marangoni, Food Biophys. 10(4), 403–415 (2015)
J.C.B. Rocha, J.D. Lopes, M.C.N. Mascarenhas, D.B. Arellano, L.M.R. Guerreiro, R.L. da Cunha, Food Res. Int. 50(1), 318–323 (2013)
W. Limpimwong, T. Kumrungsee, N. Kato, N. Yanaka, M. Thongngam, J. Funct. Foods 39, 250–256 (2017)
L.S.K. Dassanayake, D.R. Kodali, S. Ueno, K. Sato, JAOCS, J. Am. Oil Chem. Soc. 86(12), 1163–1173 (2009)
S. Pandolsook, S. Kupongsak, J. Food Eng. 214, 182–192 (2017)
M. Ögütcü, N. Arifoglu, E. Yilmaz, JAOCS, J. Am. Oil Chem. Soc. 92, 459 (2015)
D. Perez-Martinez, C. Alvarez-Salas, M. Charo-Alonso, E. Dibildox-Alvarado, J.F. Toro-Vazquez, Food Res. Int. 40(1), 47–62 (2007)
S. Martini, C.Y. Tan, S. Jana, J. Food Sci. 80(5), C989–C997 (2015)
M.D. Bin Sintang, T. Rimaux, D. Van de Walle, K. Dewettinck, A.R. Patel, Eur. J. Lipid Sci. Technol. 119(1) (2017)
E. Kesselman, E. Shimoni, Food Biophys. 2(2-3), 117–123 (2007)
A.G. Marangoni, S.H.J. Idziak, J.W.E. Rush, Food Biophys. 3(2), 241–245 (2008)
C.H. Chen, E.M. Terentjev, Langmuir 25(12), 6717–6724 (2009)
D.C.Z. Botega, A.G. Marangoni, A.K. Smith, H.D. Goff, J. Food Sci. 78, 1845 (2013)
E. Panagiotopoulou, T. Moschakis, E. Katsanidis, LWT - food Sci. Technol. 73, 351 (2016)
A.K. Zetzl, A.G. Marangoni, S. Barbut, Food Funct. 3(3), 327–337 (2012)
H.S. Hwang, M. Singh, E.L. Bakota, J.K. Winkler-Moser, S. Kim, S.X. Liu, JAOCS, J. Am. Oil Chem. Soc. 90(11), 1705–1712 (2013)
M. Ögutcu, E. Yilmaz, Grasas Aceites 65, 1 (2014)
E. Yilmaz, M. Ogutcu, R. Soc, Chem. 5, 50259 (2015)
T. Moschakis, I. Dergiade, A. Lazaridou, C.G. Biliaderis, E. Katsanidis, J. Funct. Foods 33, 386–395 (2017)
T. Moschakis, E. Panagiotopoulou, E. Katsanidis, LWT - food Sci. Technol. 73, 153 (2016)
F.Y. Ushikubo, R.L. Cunha, Food Hydrocoll. 34, 145–153 (2014)
J.F. Toro-Vazquez, R. Mauricio-Pérez, M.M. González-Chávez, M. Sánchez-Becerril, J.d.J. Ornelas-Paz, J.D. Pérez-Martínez, Food Res. Int. 54(2), 1360–1368 (2013)
A.R. Patel, D. Schatteman, W.H. De Vos, A. Lesaffer, K. Dewettinck, J. Colloid Interface Sci. 411, 114–121 (2013)
A. Singh, F.I. Auzanneau, M.A. Rogers, Food Res. Int. 97, 307–317 (2017)
L. Sagalowicz, M.E. Leser, H.J. Watzke, M. Michel, Trends Food Sci. Technol. 17(5), 204–214 (2006)
M.A. Cerqueira, L.H. Fasolin, C.S.F. Picone, L.M. Pastrana, R.L. Cunha, A.A. Vicente, Food Res. Int. 96, 161–170 (2017)
A.I. Blake, A.G. Marangoni, Food Struct. 3, 30–34 (2015)
C.D. Doan, V.D.W. Davy, A.R. Patel, K. Dewettinck, J. Am. Oil Chem. Soc. 92(6), 801–811 (2015)
H.-S. Hwang, K. Sanghoon, M. Singh, J.K. Winkler-Moser, S.X. Liu, J. Am. Oil Chem. Soc. 89(4), 639–647 (2012)
J.F. Toro-Vazquez, J.A. Morales-Rueda, E. Dibildox-Alvarado, M. Charó-Alonso, M. Alonzo-Macias, M.M. González-Chávez, JAOCS, J. Am. Oil Chem. Soc. 84(11), 989–1000 (2007)
G.M. de Oliveira, A.P.B. Ribeiro, T.G. Kieckbusch, LWT Food Sci. Technol. 63(2), 1155–1162 (2015)
M. Chopin-Doroteo, J.A. Morales-Rueda, E. Dibildox-Alvarado, M.A. Charó-Alonso, A. de la Peña-Gil, J.F. Toro-Vazquez, Food Biophys. 6(3), 359–376 (2011)
J.F. Toro-Vazquez, M. Alonzo-Macias, E. Dibildox-Alvarado, M.A. Charó-Alonso, Food Biophys. 4(3), 199–212 (2009)
X. Chen, K. Liu, P. He, H. Zhang, Y. Fang, Langmuir 28(25), 9275–9281 (2012)
C.D. Doan, I. Tavernier, S. Danthine, T. Rimaux, K. Dewettinck, J. Sci. Food Agric. 98(3), 1042–1051 (2018)
R.M. Kerr, X. Tombokan, S. Ghosh, S. Martini, J. Agric. Food Chem. 59(6), 2689–2695 (2011)
T.L.T. da Silva, D.B. Arellano, S. Martini, J. Am. Oil Chem. Soc. 95(7), 797–811 (2018)
A.C.K. Sato, R.L. da Cunha, Ciência e Tecnol. Aliment. 27(4), 890–896 (2007)
J. F. Steffe, Rheological methods in food process engineering, second (freeman press, East Lansing, MI, USA, 1996)
J.V. Kadamne, E.A. Ifeduba, C.C. Akoh, S. Martini, J. Am. Oil Chem. Soc. 94(1), 3–18 (2017)
S. Rønholt, A.S. Madsen, J.J.K. Kirkensgaard, K. Mortensen, J.C. Knudsen, Food Struct. 2(1-2), 14–26 (2014)
S. Rønholt, J.J.K. Kirkensgaard, K. Mortensen, J.C. Knudsen, Food Hydrocoll. 34, 169–176 (2014)
F.C. Wang, A.G. Marangoni, RSC Adv. 5(54), 43121–43129 (2015)
M.P. Pérez, J.R. Wagner, A.L. Márquez, J. Am. Oil Chem. Soc. 93(6), 793–801 (2016)
A. Pawlik, D. Kurukji, I. Norton, F. Spyropoulos, Food Funct. 7(6), 2712–2721 (2016)
R. Rafanan and D. Rousseau, 99, 355 (2017)
A. Bot, Y.S.J. Veldhuizen, R. den Adel, E.C. Roijers, Food Hydrocoll. 23(4), 1184–1189 (2009)
J.F. Toro-Vazquez, J. Morales-Rueda, A. Torres-Martínez, M.A. Charó-Alonso, V.A. Mallia, R.G. Weiss, Langmuir 29(25), 7642–7654 (2013)
Acknowledgements
The authors would like the express their gratitude for the Department of Nutrition, Dietetics, and Food Science of Utah State University and Capes for the international scholarship (n° 88881.134926/2016-01). This research was supported by the Utah Agricultural Experiment Station, Utah State University, and approved as journal paper number 9047.
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da Silva, T.L.T., Arellano, D.B. & Martini, S. Effect of Water Addition on Physical Properties of Emulsion Gels. Food Biophysics 14, 30–40 (2019). https://doi.org/10.1007/s11483-018-9554-3
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DOI: https://doi.org/10.1007/s11483-018-9554-3