Abstract
In this study, La(OH)3-modified magnetic sodium carboxymethyl cellulose (La-MC) was prepared as adsorbents for phosphate, which exhibited excellent adsorption performance up to 62.98 mg P/g and magnetic property for easy recovery. The recovered adsorbents after phosphate sorption were subsequently used for photocatalytic reduction of Cr(VI) and possessed good photocatalytic activity. This work provided an excellent reference for developing a new way of extending life cycle of adsorbents by combining phosphate adsorption with photocatalysis for sequential removal of pollutants from water in the future.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Bhatnagar A, Jain A (2005) A comparative adsorption study with different industrial wastes as adsorbents for the removal of cationic dyes from water. J Colloid Interface Sci 281(1):49–55. https://doi.org/10.1016/j.jcis.2004.08.076
Dai L, Wu B, Tan F, He M, Wang W, Qin H, Tang X, Zhu Q, Pan K, Hu Q (2014) Engineered hydrochar composites for phosphorus removal/recovery: lanthanum doped hydrochar prepared by hydrothermal carbonization of lanthanum pretreated rice straw. Bioresour Technol 161:327–332. https://doi.org/10.1016/j.biortech.2014.03.086
Drenkova-Tuhtan A, Schneider M, Franzreb M, Meyer C, Gellermann C, Sextl G, Mandel K, Steinmetz H (2017) Pilot-scale removal and recovery of dissolved phosphate from secondary wastewater effluents with reusable ZnFeZr adsorbent@ Fe3O4/SiO2 particles with magnetic harvesting. Water Res 109:77–87. https://doi.org/10.1016/j.watres.2016.11.039
Fang L, Wu B, Chan JK, Lo IM (2018) Lanthanum oxide nanorods for enhanced phosphate removal from sewage: a response surface methodology study. Chemosphere 192:209–216. https://doi.org/10.1016/j.chemosphere.2017.10.154
Haghseresht F, Wang S, Do D (2009) A novel lanthanum-modified bentonite, Phoslock, for phosphate removal from wastewaters. Appl Clay Sci 46(4):369–375. https://doi.org/10.1016/j.clay.2009.09.009
Huang W, Zhu Y, Tang J, Yu X, Wang X, Li D, Zhang Y (2014) Lanthanum-doped ordered mesoporous hollow silica spheres as novel adsorbents for efficient phosphate removal. J Mater Chem A 2(23):8839–8848. https://doi.org/10.1039/C4TA00326H
Jiang M-q, Jin X-y, Lu X-Q, Chen Z-l (2010) Adsorption of Pb (II), Cd (II), Ni (II) and Cu (II) onto natural kaolinite clay. Desalination 252(1–3):33–39. https://doi.org/10.1016/j.desal.2009.11.005
Jiang D, Amano Y, Machida M (2017) Removal and recovery of phosphate from water by a magnetic Fe3O4@ ASC adsorbent. J Environ Chem Eng 5(5):4229–4238. https://doi.org/10.1016/j.jece.2017.08.007
Jiang Y-H, Li A-Y, Deng H, Ye C-H, Li Y (2019) Phosphate adsorption from wastewater using ZnAl-LDO-loaded modified banana straw biochar. Environ Sci Pollut Res 26(18):18343–18353. https://doi.org/10.1007/s11356-019-05183-1
Kuroki V et al (2014) Use of a La (III)-modified bentonite for effective phosphate removal from aqueous media. J Hazard Mater 274:124–131. https://doi.org/10.1016/j.jhazmat.2014.03.023
Liao T, Li T, Su X, Yu X, Song H, Zhu Y, Zhang Y (2018) La(OH)3-modified magnetic pineapple biochar as novel adsorbents for efficient phosphate removal. J Bioresour Technol 263:207–213. https://doi.org/10.1016/j.biortech.2018.04.108
Liu J, Zhou Q, Chen J, Zhang L, Chang N (2013) Phosphate adsorption on hydroxyl–iron–lanthanum doped activated carbon fiber. Chem Eng J 215:859–867. https://doi.org/10.1016/j.cej.2012.11.067
Liu X, Lin B, Zhang Z, Lei H, Li Y (2016) Copper (II) carboxymethylcellulose (CMC-Cu II) as an efficient catalyst for aldehyde–alkyne–amine coupling under solvent-free conditions. RSC Adv 6(97):94399–94407. https://doi.org/10.1039/C6RA18742K
Marinho BA, Cristóvão RO, Djellabi R, Loureiro JM, Boaventura RAR, Vilar VJP (2017) Photocatalytic reduction of Cr (VI) over TiO2-coated cellulose acetate monolithic structures using solar light. Appl Catal B 203:18–30. https://doi.org/10.1016/j.apcatb.2016.09.061
Nagarjuna R, Challagulla S, Ganesan R, Roy S (2017) High rates of Cr (VI) photoreduction with magnetically recoverable nano-Fe3O4@ Fe2O3/Al2O3 catalyst under visible light. Chem Eng J 308:59–66. https://doi.org/10.1016/j.cej.2016.09.044
Ping N, Hans-Jörg B, Bing L, Xiwu L, ZHANG Y (2008) Phosphate removal from wastewater by model-La (III) zeolite adsorbents. J Environ Sci 20(6):670–674. https://doi.org/10.1016/S1001-0742(08)62111-7
Qin K, Li F, Xu S, Wang T, Liu C (2017) Sequential removal of phosphate and cesium by using zirconium oxide: a demonstration of designing sustainable adsorbents for green water treatment. Chem Eng J 322:275–280. https://doi.org/10.1016/j.cej.2017.04.046
Shi W, Fu Y, Jiang W, Ye Y, Kang J, Liu D, Ren Y, Li D, Luo C, Xu Z (2019) Enhanced phosphate removal by zeolite loaded with Mg–Al–La ternary (hydr) oxides from aqueous solutions: performance and mechanism. Chem Eng J 357:33–44. https://doi.org/10.1016/j.cej.2018.08.003
Sud D, Mahajan G, Kaur M (2008) Agricultural waste material as potential adsorbent for sequestering heavy metal ions from aqueous solutions—a review. Bioresour Technol 99(14):6017–6027. https://doi.org/10.1016/j.biortech.2007.11.064
Tian S, Jiang P, Ning P, Su Y (2009) Enhanced adsorption removal of phosphate from water by mixed lanthanum/aluminum pillared montmorillonite. Chem Eng J 151(1–3):141–148. https://doi.org/10.1016/j.cej.2009.02.006
Vaghetti JC et al (2009) Pecan nutshell as biosorbent to remove Cu (II), Mn (II) and Pb (II) from aqueous solutions. J Hazard Mater 162(1):270–280. https://doi.org/10.1016/j.jhazmat.2008.05.039
Velegraki G, Miao J, Drivas C, Liu B, Kennou S, Armatas GS (2018) Fabrication of 3D mesoporous networks of assembled CoO nanoparticles for efficient photocatalytic reduction of aqueous Cr (VI). Appl Catal B 221:635–644. https://doi.org/10.1016/j.apcatb.2017.09.064
Vikrant K, Kim KH, Ok YS, Tsang DCW, Tsang YF, Giri BS, Singh RS (2018) Engineered/designer biochar for the removal of phosphate in water and wastewater. Sci Total Environ 616:1242–1260. https://doi.org/10.1016/j.scitotenv.2017.10.193
Wu B, Fang L, Fortner JD, Guan X, Lo IM (2017) Highly efficient and selective phosphate removal from wastewater by magnetically recoverable La (OH)3/Fe3O4 nanocomposites. Water Res 126:179–188. https://doi.org/10.1016/j.watres.2017.09.034
Xie J, Lin Y, Li C, Wu D, Kong HJPT (2015) Removal and recovery of phosphate from water by activated aluminum oxide and lanthanum oxide. J Powder Technol 269:351–357. https://doi.org/10.1016/j.powtec.2014.09.024
Xie B, Shan C, Xu Z, Li X, Zhang X, Chen J, Pan B (2017) One-step removal of Cr (VI) at alkaline pH by UV/sulfite process: reduction to Cr (III) and in situ Cr (III) precipitation. Chem Eng J 308:791–797. https://doi.org/10.1016/j.cej.2016.09.123
Xiong W, Tong J, Yang Z, Zeng G, Zhou Y, Wang D, Song P, Xu R, Zhang C, Cheng M (2017) Adsorption of phosphate from aqueous solution using iron-zirconium modified activated carbon nanofiber: performance and mechanism. J Colloid Interface Sci 493:17–23. https://doi.org/10.1016/j.jcis.2017.01.024
Yang Q, Wang X, Luo W, Sun J, Xu Q, Chen F, Zhao J, Wang S, Yao F, Wang D, Li X, Zeng G (2018) Effectiveness and mechanisms of phosphate adsorption on iron-modified biochars derived from waste activated sludge. Bioresour Technol 247:537–544. https://doi.org/10.1016/j.biortech.2017.09.136
Zhang J, Shen Z, Shan W, Mei Z, Wang W (2011) Adsorption behavior of phosphate on lanthanum (III)-coordinated diamino-functionalized 3D hybrid mesoporous silicates material. J Hazard Mater 186(1):76–83. https://doi.org/10.1016/j.jhazmat.2010.10.076
Zhang L, Zhou Q, Liu J, Chang N, Wan L, Chen J (2012) Phosphate adsorption on lanthanum hydroxide-doped activated carbon fiber. Chem Eng J 185:160–167. https://doi.org/10.1016/j.cej.2012.01.066
Funding
This work was financially supported by the Science and Technology Program of Guangzhou (No. 201804010400), the National Natural Science Foundation of China (No. 21706091), and the Fundamental Research Funds for the Central Universities (No. 21617426).
Author information
Authors and Affiliations
Corresponding authors
Additional information
Responsible Editor: Tito Roberto Cadaval Jr
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Electronic supplementary material
ESM 1
(DOC 8.92 mb)
Rights and permissions
About this article
Cite this article
Liao, T., Huang, P., Song, H. et al. La(OH)3-modified magnetic sodium carboxymethyl cellulose for sequential removal of pollutants: adsorption of phosphate and subsequent photocatalytical reduction of Cr(VI). Environ Sci Pollut Res 27, 40346–40354 (2020). https://doi.org/10.1007/s11356-020-09904-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-020-09904-9