Abstract
FeCl3·6H2O was anchored in the pores of a layered crystalline imine-based mesoporous covalent organic framework (TPB-DMTP-COF) with surface area of 1200 m2/g and pores of 34 Å, affording the material FeCl3@TPB-DMTP-COF that worked as iron based heterogeneous catalyst. This new porous material was used in the decarboxylative oxidation cross-coupling reaction of cinnamic acids showing good to excellent catalytic activity with good chemical yields and short reaction time. FeCl3@TPB-DMTP-COF exhibit moderate surface area (235 m2/g) and high thermal and chemical stability allowing it use for several catalytic cycles.
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Acknowledgements
This research is partly supported by CNPq, CAPES and FAPERJ. PME acknowledge INOMAT for support. We dedicate this manuscript to Prof. George A. Olah.
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Supplementary material 1. Detailed synthetic procedures, spectra of reaction products and extra material characterization. (DOC 5277 KB)
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Cifuentes, J.M.C., Ferreira, B.X., Esteves, P.M. et al. Decarboxylative Cross-Coupling of Cinnamic Acids Catalyzed by Iron-Based Covalent Organic Frameworks. Top Catal 61, 689–698 (2018). https://doi.org/10.1007/s11244-018-0910-9
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DOI: https://doi.org/10.1007/s11244-018-0910-9