Skip to main content
SpringerLink
Log in

Nickel Nanoparticles Stabilized by Luminescent Labile Ligands

  • Original Paper
  • Published:
Topics in Catalysis Aims and scope Submit manuscript

Abstract

Nickel nanoparticles (NPs) have been synthesized through the microwave decomposition of Ni(η4-C8H12)2 in the presence of o,p-tBu-protected salicylamide ligands with one (LH1) or two arms (LH2). The nanoparticle colloidal dispersions are stable in ethanol. The presence of ligand on Ni surface is confirmed by the UV–Vis spectroscopy, fluorescence and mass spectrometry. Furthermore, the surface ligands can easily react with metal cations to form complexes as demonstrated from the luminescence of Tb(III) complexes. Depending on the ligand, the complexes are washed away from Ni NP surface or grafted on the surface. These hybrid structures are versatile building blocks, easily dispersible in polar solvents, luminescent and magnetic.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Jia C-J, Schüth F (2011) Phys Chem Chem Phys 13:2457

    Article  CAS  Google Scholar 

  2. Haslam GE, Chin X-Y, Burstein GT (2011) Phys Chem Chem Phys 13:12968–12974

    Article  CAS  Google Scholar 

  3. Metin O, Mazumder V, Ozkar S, Sun S (2010) J Am Chem Soc 132:1468

    Article  CAS  Google Scholar 

  4. Alonso F, Riente P, Yus M (2011) Acc Chem Res 44:379

    Article  CAS  Google Scholar 

  5. Park J, Kang E, Son SU, Park HM, Lee MK, Kim J, Kim KW, Noh H-J, Park J-H, Bae CJ, Park J-G, Hyeon T (2005) Adv Mater 17:429

    Article  CAS  Google Scholar 

  6. Ramirez E, Jansat S, Philippot K, Lecante P, Gomez M, Masdeu-Bultó AM, Chaudret B (2004) J Organometal Chem 689:4601–4610

    Article  CAS  Google Scholar 

  7. Durand J, Teuma E, Gómez M. (2008) Eur J Inorg Chem 23:3577–3586

    Google Scholar 

  8. Astruc D, Lu F, Aranzaes JR (2005) Angew Chem Int Ed 44:7852–7872

    Article  CAS  Google Scholar 

  9. De Caro D, Bradley JS (1997) Langmuir 13:3067

    Article  Google Scholar 

  10. Ely TO, Amiens C, Chaudret B, Snoeck E, Verelst M, Respaud M, Broto J-M (1999) Chem Mater 11:526

    Article  CAS  Google Scholar 

  11. Migowski P, Machado G, Texeira SR, Alves MCM, Morais J, Traverse A, Dupont J (2007) Phys Chem Chem Phys 9:4814

    Article  CAS  Google Scholar 

  12. Ramírez-Meneses E, Betancourt I, Morales F, Montiel-Palma V, Villanueva-Alvarado CC, Hernández-Rojas ME (2011) J Nanopart Res 13:365

    Article  Google Scholar 

  13. Cordente N, Respaud M, Senocq F, Casanove M-J, Amiens C, Chaudret B (2001) Nano Lett 1:565

    Article  CAS  Google Scholar 

  14. Shviro M, Zitoun D (2012) Nanoscale 4:762

    Article  CAS  Google Scholar 

  15. Shviro M, Zitoun D (2013) RSC Advances 3:1380

    Article  CAS  Google Scholar 

  16. Benisvy L, Gamez P, Fu WT, Kooijman H, Spek AL, Meijerink A, Reedijk J (2008) Dalton Trans 24:3147

  17. Samuel APS, Xu J, Raymond KN (2009) Inorg Chem 48:687

    Article  CAS  Google Scholar 

  18. Wanke R, Benisvy L, Kuznetsov ML, Guedes da Silva MFC, Pombeiro AJL (2011) Chem Eur J 17:11882

    Article  CAS  Google Scholar 

  19. Eckshtain M, Lavi R, Yufit DS, Arora H, Daniel B, Green O, Richman M, Rahimipour S, Gruzman A, Benisvy L (2013) ChemBioChem, submitted

  20. Tsai C-J, Chen C-N, Tseng WJ (2011) J Nanoparticle Res 13:6859

    Article  CAS  Google Scholar 

  21. Yuen AKL, Hutton GA, Masters AF, Maschmeyer T (2012) Dalton Trans 41:2545–2559

    Article  CAS  Google Scholar 

  22. Winter A, Hager MD, Newkome GR, Schubert US (2011) Adv Mater 23:5728–5748

    Article  CAS  Google Scholar 

  23. Wang Y, Weinstock IA (2012) Chem Soc Rev 41:7479–7496

    Article  CAS  Google Scholar 

  24. Daniel M-C, Astruc D (2004) Chem Rev 104:293–346

    Article  CAS  Google Scholar 

  25. Parker JF, Fields-Zinna CA, Murray RW (2010) Acc Chem Res 43:1289–1296

    Article  CAS  Google Scholar 

  26. Lim SI, Zhong C-J (2009) Acc Chem Res 42:798–808

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Bar Ilan Institute of Nanotechnology and Advanced Materials, Bar Ilan University, 52900, Ramat Gan, Israel

    Meital Shviro, Meital Eckshtain-Levi, Laurent Benisvy & David Zitoun

Authors
  1. Meital Shviro
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Meital Eckshtain-Levi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Laurent Benisvy
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. David Zitoun
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Laurent Benisvy or David Zitoun.

Additional information

Meital Shviro and Meital Eckshtain-Levi equally contributed to this study.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shviro, M., Eckshtain-Levi, M., Benisvy, L. et al. Nickel Nanoparticles Stabilized by Luminescent Labile Ligands. Top Catal 56, 1184–1191 (2013). https://doi.org/10.1007/s11244-013-0084-4

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11244-013-0084-4

Keywords

Search

Navigation