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Electrochemical phosphorylation of coumarins catalyzed by transition metal complexes (Ni—Mn, Co—Mn)

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Abstract

A possibility of electrochemical phosphorylation of coumarins (coumarin, 6-methylcoumarin, 7-methylcoumarin) with diethyl phosphite was shown. The approach is based on the oxidation of a mixture of the aromatic compound and diethyl phosphite (1: 1) under mild conditions (room temperature, atmospheric pressure) in the presence of a bimetallic catalytic systems: MnIIbipy/NiIIbipy and MnIIbipy/CoIIbipy (bipy is the 2,2´-bipyridine). This method allows one to obtain diethyl arylphosphonates in high yields (up to 70%) and 100% conversion of the phosphite.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    S. O. Strekalova, M. N. Khrizanforov, T. V. Gryaznova, V. V. Khrizanforova & Yu. H. Budnikova

Authors
  1. S. O. Strekalova
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  2. M. N. Khrizanforov
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  3. T. V. Gryaznova
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  4. V. V. Khrizanforova
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  5. Yu. H. Budnikova
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Correspondence to M. N. Khrizanforov.

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Dedicated to Academician of the Russian Academy of Sciences O. G. Sinyashin on the occasion of his 60th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1295–1298, May, 2016.

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Strekalova, S.O., Khrizanforov, M.N., Gryaznova, T.V. et al. Electrochemical phosphorylation of coumarins catalyzed by transition metal complexes (Ni—Mn, Co—Mn). Russ Chem Bull 65, 1295–1298 (2016). https://doi.org/10.1007/s11172-016-1451-7

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  • DOI: https://doi.org/10.1007/s11172-016-1451-7

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