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Nanomagnetically modified polyphosphoric acid (NiFe2O4@SiO2–PPA): an efficient, fast, and reusable catalyst for the synthesis of 2-thioxoquinazolinones under solvent-free conditions

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Abstract

Polyphosphoric acid functionalized silica-coated magnetic nanoparticles with core–shell structure (NiFe2O4@SiO2–PPA) has been used as a magnetically recyclable green catalyst for the one-pot three-component synthesis of 2-thioxoquinazolinones by the reaction of isatoic anhydride, primary amines and thiourea under neat conditions. The catalyst is readily recovered by simple magnetic decantation and can be recycled five times with no significant loss of catalytic activity.

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Acknowledgment

The authors are grateful to Islamic Azad University, Bandar Abbas and Mashhad Branches for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad, Iran

    Hossein Eshghi & Mehdi Bakavoli

  2. Department of Chemistry, College of Science, Islamic Azad University, Mashhad Branch, Mashhad, Iran

    Amir Khojastehnezhad, Nafiseh Zeinabi & Sadegh Allameh

  3. Department of Chemistry, College of Science, Islamic Azad University, Bandar Abbas Branch, 7915893144, Bandar Abbas, Iran

    Farid Moeinpour

Authors
  1. Hossein Eshghi
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  2. Amir Khojastehnezhad
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  3. Farid Moeinpour
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  4. Mehdi Bakavoli
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  5. Nafiseh Zeinabi
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  6. Sadegh Allameh
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Correspondence to Farid Moeinpour.

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Eshghi, H., Khojastehnezhad, A., Moeinpour, F. et al. Nanomagnetically modified polyphosphoric acid (NiFe2O4@SiO2–PPA): an efficient, fast, and reusable catalyst for the synthesis of 2-thioxoquinazolinones under solvent-free conditions. Res Chem Intermed 41, 7915–7924 (2015). https://doi.org/10.1007/s11164-014-1866-4

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  • DOI: https://doi.org/10.1007/s11164-014-1866-4

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