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Catalytic oxidation of toluene over active MnO x catalyst prepared via an alkali-promoted redox precipitation method

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Abstract

MnO x catalysts were contrastively prepared by an alkali-promoted redox precipitation strategy (MnO x -RP) and a conventional citrate sol–gel method (MnO x -SG), and tested for the catalytic oxidation of toluene, where MnO x -RP exhibited higher catalytic activity, excellent catalytic durability under dry conditions and good regeneration ability under humid conditions. The characterizations results indicated that different crystalline phases but similar textual properties (specific surface area, porosity and morphology) were observed over MnO x -RP and MnO x -SG catalysts, while MnO x -RP presented significantly higher low-temperature reducibility and average oxidation state of Mn as well as higher abundance of surface adsorbed oxygen species compared with MnO x -SG, thus beneficially resulting in its superior catalytic activity in the reaction.

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Acknowledgments

The financial supports from National Natural Science Foundation of China (Grant No. 21307009, 21276263) are gratefully acknowledged.

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Authors and Affiliations

  1. Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou, 213164, People’s Republic of China

    Lei Wang, Wei Zhang, Mohong Lu & Mingshi Li

  2. Key Laboratory of Biofuels, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101, People’s Republic of China

    Lei Wang, Chuanhui Zhang, He Huang & Xuebing Li

Authors
  1. Lei Wang
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  2. Chuanhui Zhang
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  3. He Huang
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  4. Xuebing Li
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  5. Wei Zhang
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  6. Mohong Lu
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  7. Mingshi Li
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Correspondence to Mingshi Li.

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Wang, L., Zhang, C., Huang, H. et al. Catalytic oxidation of toluene over active MnO x catalyst prepared via an alkali-promoted redox precipitation method. Reac Kinet Mech Cat 118, 605–619 (2016). https://doi.org/10.1007/s11144-016-1011-z

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  • DOI: https://doi.org/10.1007/s11144-016-1011-z

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