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TG/DTG/DTA for the oxidation behavior characterization of vegetable and animal fats

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Abstract

TG/DTG/DTA curves can be used to estimate alimentary fats quality and antioxidants insertion efficiency. Sunflower oil obtained from Carnia hybrid and pork lard were used as matrices for the non-isothermal measurements. The first stage of non-isothermal decomposition is mostly important for the characterization of the fats thermal stability. The corresponding onset temperature is a good value for the comparison of different fats thermal stability or for the effectiveness evaluation in case of antioxidant insertion. In this study, it can be seen a considerable improvement of the fats thermal stability by adding small amounts from a natural antioxidant liquid mixture (obtained by alcoholic maceration of equal amounts of seven plants, namely: milfoil, rosemary, marjoram, thyme, lovage, oregano, and basil). Chlorophylls removal from the plant extract using two different adsorbents was accompanied by a four time decrease of the antiradical activity (measured by the DPPH method) with Sephadex LH20 and seventeen times decrease when activated carbon was used.

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References

  1. de Souza AG, Santos JC, Conceição MM, Silva MCD, Prasad S. A thermoanalytic and kinetic study of sunflower oil. Braz J Chem Eng. 2004;21(2):265–73.

    Article  Google Scholar 

  2. Araújo KLGV, Epaminondas PS, Silva MCD, de Lima AEA, Rosenhaim R, Maia AS, Soledade LEB, Souza AL, Santos IMG, Souza AG, Queiroz N. Influence of thermal degradation in the physicochemical properties of fish oil. J Therm Anal Calorim. 2011;106:557–61.

    Article  Google Scholar 

  3. López-Beceiro J, Artiaga R, Gracia C, Tarrío-Saavedra J, Naya S, Mier JL. Comparison of olive, corn, soybean and sunflower oils by PDSC. J Therm Anal Calorim. 2011;104:169–75.

    Article  Google Scholar 

  4. Giuffrida F, Destaillatsa F, Egarta MH, Huga B, Golaya P-A, Skibstedb LH, Dionisia F. Activity and thermal stability of antioxidants by differential scanning calorimetry and electron spin resonance spectroscopy. Food Chem. 2007;101(3):1108–14.

    Article  CAS  Google Scholar 

  5. Ssonko UL, Wenshui X. Food phenolics, pros and cons: a review. Food Rev Int. 2005;21(4):367–88.

    Article  Google Scholar 

  6. Mizutani T, Nomura H, Nakanishi K, Fujita S. Hepato-toxicity of butylated hydroxytoluene and its analogs in mice depleted of hepatic glutathione. Toxicol Appl Pharm. 1987;87:166–76.

    Article  CAS  Google Scholar 

  7. Williams GM, Maeura Y, Weisburger JH. Simultaneous inhibition of liver carcinogenicity and enhancement of bladder carcinogenicity of N-2-fluorenylacetamide by butylated hydroxytoluene. Cancer Lett. 1983;19:55–60.

    Article  CAS  Google Scholar 

  8. Szabo MR, Radu D, Gavrilas S, Chambre D, Iditoiu C. Antioxidant and antimicrobial properties of selected spice extracts. Int J Food Prop. 2010;13(3):535–45.

    Article  Google Scholar 

  9. Szabo MR, Iditoiu C, Chambre D, Lupea AX. Improved DPPH determination for antioxidant activity spectrophotometric assay. Chem Pap. 2007;61(3):214–6.

    Article  CAS  Google Scholar 

  10. Szabo MR, Iditoiu C, Chambre D. New method for the calculus of the antioxidant activity in the DPPH spectrophotometric assay. Sci Tech Bull Aurel Vlaicu Univ. 2006;11:122–5.

    Google Scholar 

  11. Szabo MR, Iditoiu C, Chambre D, Lupea AX. Antiradical activity of some plants used in the Romanian cuisine. Int J Food Prop. 2008;2:330–8.

    Article  Google Scholar 

  12. Vieira T, Regitano-D’Arce M. Stability of oils heated by microwave: UV-spectrophotometric evaluation. Ciencia Tecnol Alime. 1998;18(4):433–7.

    Article  CAS  Google Scholar 

  13. Vecchio S, Campanella L, Nuccilli A, Tomassetti M. Kinetic study of thermal breakdown of triglycerides contained in extra-virgin olive oil. J Therm Anal Calorim. 2008;91(1):51–6.

    Article  CAS  Google Scholar 

  14. Balaban AT, Pogany I, Banciu M. Aplicatii ale metodelor fizice in chimia organica. Bucuresti: Ed. Stiintifica si Enciclopedica; 1983.

    Google Scholar 

  15. Pons WA, Kuck JC, Frampton VL. Bleaching of refined cottonseed oil with modified alumina absorbents. J Amer Oil Chem Soc. 1963;40(1):10–3.

    Article  CAS  Google Scholar 

  16. Cacig S. Possibilities to use vegetable extracts as natural ingredients for drugs, cosmetics and food (in Romanian), PhD Thesis Timisoara: Ed. Politehnica; 2007.

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Correspondence to Dorina Chambre or Cornelia Idiţoiu.

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Szabo, MR., Chambre, D. & Idiţoiu, C. TG/DTG/DTA for the oxidation behavior characterization of vegetable and animal fats. J Therm Anal Calorim 110, 281–285 (2012). https://doi.org/10.1007/s10973-012-2253-2

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